Contact us: +91 9550333722 040 - 40102781
Structured search
India
Choose your country
Different countries will display different contents
Try our best to find the right business for you.
My chemicalbook

Welcome back!

HomeProduct name listCopper(I) bromide-dimethyl sulfide

Copper(I) bromide-dimethyl sulfide

Synonym(s):Copper(I) bromide methyl sulfide complex;Cuprous bromide dimethyl sulfide complex;Cuprous bromide methyl sulfide complex

  • CAS NO.:54678-23-8
  • Empirical Formula: C2H6BrCuS
  • Molecular Weight: 205.58
  • MDL number: MFCD00043295
  • EINECS: 259-292-5
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-11-01 18:09:03
Copper(I) bromide-dimethyl sulfide Structural

What is Copper(I) bromide-dimethyl sulfide?

Chemical properties

off-white to beige, grey or green crystalline

The Uses of Copper(I) bromide-dimethyl sulfide

Copper(I) bromide-dimethyl sulfide can be used as catalyst for adding Grignard reagents to fullerenes.

The Uses of Copper(I) bromide-dimethyl sulfide

Copper(I) bromide-dimethyl sulfide complex is used as catalyst for adding Grignard reagents to fullerenes.

The Uses of Copper(I) bromide-dimethyl sulfide

Catalyst employed in the addition of Grignard reagents (alkyl, alkenyl, aryl) to fullerenes. This process adds 5 organic groups to [60]fullerene and 3 groups to [70]fullerene.

Purification Methods

Purify it by recrystallisation in the presence of Me2S. A solution of the complex (1.02g) in Me2S (5mL) is slowly diluted with hexane (20mL), and the pure colourless prisms of the complex (0.96g) separate and are collected and dried, m 124-129o(dec). The complex is insoluble in hexane, Et2O, Me2CO, CHCl3 and CCl4. It dissolves in DMF and DMSO, but the solution becomes hot and green indicating decomposition. It dissolves in *C6H6, Et2O, MeOH and CHCl3 if excess of Me2S is added and a colourless solution is obtained. [House et al. J Org Chem 40 1460 1975.] Prior to use, the complex is dissolved in Me2S and evaporated to dryness in the weighed reaction flask [Bourgain-Commer.on et al. J Organomet Chem 228 321 1983].

Properties of Copper(I) bromide-dimethyl sulfide

Melting point: 132 °C (dec.)(lit.)
form  Crystalline Powder and/or Chunks
color  Pale brown or pale green
Water Solubility  Soluble in water. Reacts with water and decomposes.
Sensitive  Moisture Sensitive/Air Sensitive
BRN  4386581
Exposure limits ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3
CAS DataBase Reference 54678-23-8(CAS DataBase Reference)

Safety information for Copper(I) bromide-dimethyl sulfide

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Copper(I) bromide-dimethyl sulfide

InChIKey PMHQVHHXPFUNSP-UHFFFAOYSA-M

Related products of tetrahydrofuran

You may like

  • 54678-23-8 Copper(I) bromide dimethyl sulfide complex 95%
    54678-23-8 Copper(I) bromide dimethyl sulfide complex 95%
    54678-23-8
    View Details
  • Copper(I) bromide-dimethyl sulfide complex CAS 54678-23-8
    Copper(I) bromide-dimethyl sulfide complex CAS 54678-23-8
    54678-23-8
    View Details
  • Copper(I) bromide-dimethyl sulfide complex CAS 54678-23-8
    Copper(I) bromide-dimethyl sulfide complex CAS 54678-23-8
    54678-23-8
    View Details
  • Copper(I) bromide-dimethyl sulfide complex CAS 54678-23-8
    Copper(I) bromide-dimethyl sulfide complex CAS 54678-23-8
    54678-23-8
    View Details
  • Copper(I) bromide-dimethyl sulfide complex 98.00% CAS 54678-23-8
    Copper(I) bromide-dimethyl sulfide complex 98.00% CAS 54678-23-8
    54678-23-8
    View Details
  • Copper(I) bromide dimethyl sulfide complex
    Copper(I) bromide dimethyl sulfide complex
    54678-23-8
    View Details
  • Copper(i) bromide-dimethyl sulfide 98% CAS 54678-23-8
    Copper(i) bromide-dimethyl sulfide 98% CAS 54678-23-8
    54678-23-8
    View Details
  • Copper(I) bromide dimethyl sulfide complex CAS 54678-23-8
    Copper(I) bromide dimethyl sulfide complex CAS 54678-23-8
    54678-23-8
    View Details
Statement: All products displayed on this website are only used for non medical purposes such as industrial applications or scientific research, and cannot be used for clinical diagnosis or treatment of humans or animals. They are not medicinal or edible.