SILVER NITRITE

Synonym(s):Silver nitrite (AgNO);Silver(I) nitrite

CAS NO.：7783-99-5
Empirical Formula: AgNO2
Molecular Weight: 153.87
MDL number: MFCD00003413
EINECS: 232-041-7
SAFETY DATA SHEET (SDS)
Update Date: 2023-10-17 17:11:57

What is SILVER NITRITE?

Chemical properties

powder

The Uses of SILVER NITRITE

Silver nitrite is used in the silver plating process, hair dye, inks, permanent marker pens and determination of chloride ions in water and drilling fluids. It is used as Tollen?s reagent and used in the formation of aniline and nitro compounds in victor mayer reactions.

The Uses of SILVER NITRITE

For preparation of standard NaNO2 solution for water analysis; preparation of aliphatic nitro-compounds; as reagent for primary, secondary, and tertiary alcohols.

Hazard

Highly toxic.

Purification Methods

Crystallise the salt from hot conductivity water (70mL/g) in the dark. Dry it in the dark under vacuum. [Glemser & Sauer in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 1048 1963.]

Properties of SILVER NITRITE

Melting point:	140 °C (lit.)
Density	4.453 g/mL at 25 °C (lit.)
solubility	insoluble in ethanol; reacts with acid solutions
form	Powder and Agglomerates
color	Yellow-green
Specific Gravity	4.453
Water Solubility	Soluble in hot water.Insoluble in ethanol.
Sensitive	Light Sensitive
Merck	14,8519
Solubility Product Constant (Ksp)	pKsp: 3.22
Exposure limits	ACGIH: TWA 0.01 mg/m3 NIOSH: IDLH 10 mg/m3; TWA 0.01 mg/m3
Stability:	Stable. Oxidizer - contact with combustible material may cause fire.
CAS DataBase Reference	7783-99-5(CAS DataBase Reference)
EPA Substance Registry System	Nitrous acid, silver(1+) salt (7783-99-5)

Safety information for SILVER NITRITE

Signal word	Danger
Pictogram(s)	Flame Over Circle Oxidizers GHS03 Skull and Crossbones Acute Toxicity GHS06 Environment GHS09
GHS Hazard Statements	H272:Oxidising liquids;Oxidising solids H301:Acute toxicity,oral H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H410:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes	P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P220:Keep/Store away from clothing/…/combustible materials. P273:Avoid release to the environment. P301+P310:IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.