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HomeProduct name listSilicon nitride

Silicon nitride

Synonym(s):SI536020;Silicon nitride;Trisilicon tetranitride

  • CAS NO.:12033-89-5
  • Empirical Formula: N4Si3
  • Molecular Weight: 140.2833
  • MDL number: MFCD00011230
  • EINECS: 234-796-8
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-07-30 17:43:28
Silicon nitride Structural

What is Silicon nitride?

Chemical properties

slightly beige powder

Physical properties

Gray amorphous powder or crystals. Resistant to thermal shock. Good oxidation resistance up to 1500°C but decomposes into nitrogen and silicon above 1850°C. Excellent corrosion resistance to molten nonferrous metals such as Al, Pb, Zn, Cd, Bi, Rb, and Sn, and molten salts like NaCl-KCl, NaF, and silicate glasses. However, corroded by molten Mg, Ti, V, Cr, Fe, and Co, cryolite, KOH, and Na2 O.

The Uses of Silicon nitride

Silicon nitride (Si3N4), resistant to oxidation, is an excellent coating for metals, as well as an adhesive and abrasive, and it is used in high-temperature crucibles. It has proven useful as heat-resistant substance for the nozzles on rocket engines.

The Uses of Silicon nitride

As high tempereture engineering material for use in gas turbines, diesel engines.

The Uses of Silicon nitride

Silicon Nitride is used in preparation of thermal conductive Poly(Me Methacrylate)/Silicon Nitride nanocomposites via click chemistry.

General Description

Silicon nitride based ceramics possess high fracture toughness, hardness and wear resistance, resistance to corrosion, thermal stability. Two known polymorphs of silicon nitride exist, alpha and beta Si3N4, both have hexagonal structure. A study shows that a third state, cubic spinel structure, has also been synthesized.

Flammability and Explosibility

Non flammable

Properties of Silicon nitride

Melting point: 1900 °C
Density  3.44 g/mL at 25 °C (lit.)
refractive index  2.8
RTECS  VW0650000
form  powder
color  Pale gray
Specific Gravity 3.44
Resistivity 10*6 (ρ/μΩ.cm)
Water Solubility  Insoluble water.
Hydrolytic Sensitivity 1: no significant reaction with aqueous systems
Crystal Structure Hexagonal
Merck  14,8497
Stability: Stable.
CAS DataBase Reference 12033-89-5(CAS DataBase Reference)
EPA Substance Registry System Silicon nitride (Si3N4) (12033-89-5)

Safety information for Silicon nitride

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
Precautionary Statement Codes P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313:IF SKIN irritation occurs: Get medical advice/attention.
P337+P313:IF eye irritation persists: Get medical advice/attention.

Computed Descriptors for Silicon nitride

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