Rhodium carbonyl chloride
Synonym(s):Rhodium carbonyl chloride(I);Rhodium(I) carbonyl chloride;Rhodium(I) dicarbonyl chloride dimer;Tetracarbonyldi-μ−chlorodirhodium(I)
- CAS NO.：14523-22-9
- Empirical Formula: 4CO.Cl2Rh2
- Molecular Weight: 388.77
- MDL number: MFCD00135610
- EINECS: 238-540-6
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-04-23 13:52:06
What is Rhodium carbonyl chloride?
Chemical properties
red to brownish crystals, crystalline powder or
The Uses of Rhodium carbonyl chloride
Rhodium Carbonyl Chloride is a reagent for rhodium-catalyzed [4+2+1] cycloaddition of in situ generated ene/yne-ene-allenes and carbon monoxide to produce [4+2+1] cycloadducts
The Uses of Rhodium carbonyl chloride
Catalyst for organic reactions.
Properties of Rhodium carbonyl chloride
| Melting point: | 120-125 °C (dec.)(lit.) |
| storage temp. | 2-8°C |
| solubility | It is soluble in organic or non-aqueous solvent. |
| form | crystal |
| color | red |
| Water Solubility | soluble in most organic solvents; insoluble aliphatic hydrocarbons [MER06] |
| Sensitive | Air & Moisture Sensitive |
| Merck | 14,8187 |
| Exposure limits | ACGIH: TWA 1 mg/m3 NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3 |
| CAS DataBase Reference | 14523-22-9(CAS DataBase Reference) |
| NIST Chemistry Reference | Dirhodium tetracarbonyl dichloride(14523-22-9) |
Safety information for Rhodium carbonyl chloride
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H302:Acute toxicity,oral |
| Precautionary Statement Codes |
P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P270:Do not eat, drink or smoke when using this product. P330:Rinse mouth. |
Computed Descriptors for Rhodium carbonyl chloride
New Products
4-AMINO-TETRAHYDRO-PYRAN-4-CARBOXYLIC ACID HCL 4-(Dimethylamino)tetrahydro-2H-pyran-4-carbonitrile 4-Aminotetrahydropyran-4-carbonitrile Hydrochloride (R)-3-Aminobutanenitrile Hydrochloride 3-((Dimethylamino)methyl)-5-methylhexan-2-one oxalate 1,4-Dioxa-8-azaspiro[4.5]decane 5-Bromo-2-nitropyridine Nimesulide BP Aceclofenac IP/BP/EP Diclofenac Sodium IP/BP/EP/USP Mefenamic Acid IP/BP/EP/USP Ornidazole IP Diclofenac Potassium THOMAIND PAPER PH 2.0 TO 4.5 1 BOX BUFFER CAPSULE PH 9.2 - 10 CAP SODIUM CHLORIDE 0.1N CVS ALLOXAN MONOHYDRATE 98% PLATINUM 0.5% ON 3 MM ALUMINA PELLETS (TYPE 73) LITHIUM AAS SOLUTION 2-Bromo-1-(bromomethyl)-3-chloro-5-nitrobenzene 2-Bromo-3-nitroaniline N-(3-Hydroxypropyl)-N-methylacetamide 3-Bromo-6-chloropyridazine 4-ethyl-3-nitrobenzoic acidRelated products of tetrahydrofuran
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