Rhodium carbonyl chloride
Synonym(s):Rhodium carbonyl chloride(I);Rhodium(I) carbonyl chloride;Rhodium(I) dicarbonyl chloride dimer;Tetracarbonyldi-μ−chlorodirhodium(I)
- CAS NO.:14523-22-9
- Empirical Formula: 4CO.Cl2Rh2
- Molecular Weight: 388.77
- MDL number: MFCD00135610
- EINECS: 238-540-6
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-04-23 13:52:06
What is Rhodium carbonyl chloride?
Chemical properties
red to brownish crystals, crystalline powder or
The Uses of Rhodium carbonyl chloride
Rhodium Carbonyl Chloride is a reagent for rhodium-catalyzed [4+2+1] cycloaddition of in situ generated ene/yne-ene-allenes and carbon monoxide to produce [4+2+1] cycloadducts
The Uses of Rhodium carbonyl chloride
Catalyst for organic reactions.
Properties of Rhodium carbonyl chloride
Melting point: | 120-125 °C (dec.)(lit.) |
storage temp. | 2-8°C |
solubility | It is soluble in organic or non-aqueous solvent. |
form | crystal |
color | red |
Water Solubility | soluble in most organic solvents; insoluble aliphatic hydrocarbons [MER06] |
Sensitive | Air & Moisture Sensitive |
Merck | 14,8187 |
Exposure limits | ACGIH: TWA 1 mg/m3 NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3 |
CAS DataBase Reference | 14523-22-9(CAS DataBase Reference) |
NIST Chemistry Reference | Dirhodium tetracarbonyl dichloride(14523-22-9) |
Safety information for Rhodium carbonyl chloride
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H302:Acute toxicity,oral |
Precautionary Statement Codes |
P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P270:Do not eat, drink or smoke when using this product. P330:Rinse mouth. |
Computed Descriptors for Rhodium carbonyl chloride
New Products
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Benzoyl peroxide
Sodium chloride
Ammonium chloride
Choline chloride
CARBONYL SULFIDE
Rhodium
Aluminum oxide
PYRAZOPHOS
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