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HomeProduct name listRhodium carbonyl chloride

Rhodium carbonyl chloride

Synonym(s):Rhodium carbonyl chloride(I);Rhodium(I) carbonyl chloride;Rhodium(I) dicarbonyl chloride dimer;Tetracarbonyldi-μ−chlorodirhodium(I)

  • CAS NO.:14523-22-9
  • Empirical Formula: 4CO.Cl2Rh2
  • Molecular Weight: 388.77
  • MDL number: MFCD00135610
  • EINECS: 238-540-6
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-04-23 13:52:06
Rhodium carbonyl chloride Structural

What is Rhodium carbonyl chloride?

Chemical properties

red to brownish crystals, crystalline powder or

The Uses of Rhodium carbonyl chloride

Rhodium Carbonyl Chloride is a reagent for rhodium-catalyzed [4+2+1] cycloaddition of in situ generated ene/yne-ene-allenes and carbon monoxide to produce [4+2+1] cycloadducts

The Uses of Rhodium carbonyl chloride

Catalyst for organic reactions.

Properties of Rhodium carbonyl chloride

Melting point: 120-125 °C (dec.)(lit.)
storage temp.  2-8°C
solubility  It is soluble in organic or non-aqueous solvent.
form  crystal
color  red
Water Solubility  soluble in most organic solvents; insoluble aliphatic hydrocarbons [MER06]
Sensitive  Air & Moisture Sensitive
Merck  14,8187
Exposure limits ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
CAS DataBase Reference 14523-22-9(CAS DataBase Reference)
NIST Chemistry Reference Dirhodium tetracarbonyl dichloride(14523-22-9)

Safety information for Rhodium carbonyl chloride

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H302:Acute toxicity,oral
Precautionary Statement Codes P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P270:Do not eat, drink or smoke when using this product.
P330:Rinse mouth.

Computed Descriptors for Rhodium carbonyl chloride

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