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HomeProduct name listDI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)

DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)

Synonym(s):[Ir(OMe)(1,5-cod)]2;Bis(1,5-cyclooctadiene)di-μ-methoxydiiridium(I)

  • CAS NO.:12148-71-9
  • Empirical Formula: C18H22Ir2O2
  • Molecular Weight: 654.81
  • MDL number: MFCD08459360
  • EINECS: 628-411-6
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-04-23 13:52:06
DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) Structural

What is DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)?

Chemical properties

yellow solid

The Uses of DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)

Methoxy(cyclooctadiene)iridium(I) dimer is used as a catalyst in the preparation of heteroaryl fused indole ring systems and borylation and Suzuki-miyaura coupling. Further, it is used in tetraborylation reactions, ortho-silylation of aryl ketone, benzaldehyde and benzyl alcohol derivatives through C-H activation. The most useful application is highly regio and enantio selection asymmetric hydroboration.

What are the applications of Application

(1,5-Cyclooctadiene)(methoxy)iridium(I) dimer is a catalyst for preparation of heteroaryl fused indole ring systems, borylation/suzuki-miyaura coupling

Properties of DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)

Melting point: 154-179 °C (D)
storage temp.  -20°C
form  Powder
color  yellow
Sensitive  Light, Air & Moisture Sensitive

Safety information for DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P271:Use only outdoors or in a well-ventilated area.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)

InChIKey WLPGZWOTJGJODI-SXGOCSEPSA-N

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