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HomeProduct name listCERIC SULFATE

CERIC SULFATE

Synonym(s):Ceric sulfate;Cerium disulfate

  • CAS NO.:13590-82-4
  • Empirical Formula: CeH2O4S
  • Molecular Weight: 238.19
  • MDL number: MFCD00148852
  • EINECS: 237-029-5
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-04-23 13:52:06
CERIC SULFATE Structural

What is CERIC SULFATE?

Chemical properties

yellow odourless solid

Physical properties

White crystalline powder; orthogonal crystal system; the tetrahydrate is a yellow-to-orange powder which, on heating at 180°C, loses all molecules of water; density of tetrahydrate 3.91 g/cm3; anhydrous salt decomposes at 350°C forming CeOSO4; soluble in water (decomposes); soluble in dilute H2SO4 and other concentrated mineral acids.

The Uses of CERIC SULFATE

calibrated against sodium oxalate, traceable to NIST SRM

The Uses of CERIC SULFATE

Cerium(IV) sulfate is a redox indicator and is used in analytical chemistry for redox titrations. In ionized form, ceric ion acts as a strong oxidizer under acidic conditions. It is also used to prepare spherical-like nanoparticles CeO2, nanoparticles for NO reductions' reactions.

What are the applications of Application

Cerium(IV) sulfate is an oxidizing agent used in analytical chemistry

Preparation

Cerium(IV) sulfate is prepared by heating cerium(IV) oxide, CeO2 with concentrated H2SO4. Also it may be obtained by the reaction of H2SO4 with cerium carbonate:
Ce(CO3)2 + 2H2SO4 + H2O → Ce(SO4)2?4H2O + 2CO2.

General Description

3S - Safe, Smart, Secure
An intelligent packaging solution protected with originality seal.
Reagent information is transferred via RFID from reagent bottle to titrator.
3S reagents are compatible only with the Metrohm Omnis titration platform.

Please see here SigmaAldrich.com/3S

Flammability and Explosibility

Not classified

Safety Profile

Experimental reproductive effects. When heated to decomposition it emits acrid smoke and irritating fumes.

Properties of CERIC SULFATE

Density  3.01 g/mL at 25 °C(lit.)
vapor pressure  0.001Pa at 20℃
storage temp.  Inert atmosphere,Room Temperature
form  Liquid
color  Light yellow
Water Solubility  Soluble in water and dilute sulfuric acid.
Sensitive  Hygroscopic
Merck  14,1990
CAS DataBase Reference 13590-82-4(CAS DataBase Reference)
EPA Substance Registry System Sulfuric acid, cerium(4+) salt (2:1) (13590-82-4)

Safety information for CERIC SULFATE

Signal word Danger
Pictogram(s)
ghs
Corrosion
Corrosives
GHS05
ghs
Environment
GHS09
GHS Hazard Statements H314:Skin corrosion/irritation
H410:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P260:Do not breathe dust/fume/gas/mist/vapours/spray.
P273:Avoid release to the environment.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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