Borane-triethylamine complex
Synonym(s):(N,N-Diethylethanamine)trihydroboron;NSC 59740;Triethylamine borane
- CAS NO.：1722-26-5
- Empirical Formula: C6H18BN
- Molecular Weight: 115.02
- MDL number: MFCD00012423
- EINECS: 217-022-3
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-12-17 15:29:29
What is Borane-triethylamine complex?
Chemical properties
clear colourless liquid
The Uses of Borane-triethylamine complex
As a reducing agent and in hydroboration reactionsBorane-triethylamine complex is used for ethanolysis of amine-borane adducts. It is also used in photochemical hydroboration and oxidation of single-walled carbon nanotubes. Further, it acts as a reactant for the synthesis of silylboranate and N-heterocyclic carbene borane complexes through Lewis base exchange with amine-boranes. It plays an important role in the generation of boron carbide nitride films through low-pressure chemical vapor deposition.
Purification Methods
Distil it in a vacuum using a 60cm glass helices-packed column. [Brown et al. J Am Chem Soc 64 325 1942, Ashby & Foster J Am Chem Soc 84 3407 1962, Matsuura & Tolcura Tetrahedron Lett 4703 1968, Beilstein 4 IV 329.]
Properties of Borane-triethylamine complex
| Melting point: | −4-−2 °C |
| Boiling point: | 97 °C12 mm Hg(lit.) |
| Density | 0.783 g/mL at 20 °C(lit.) |
| refractive index | n |
| Flash point: | 20 °F |
| storage temp. | Refrigerator |
| form | Liquid |
| color | Colorless to pale yellow |
| Water Solubility | MAY DECOMPOSE |
| Sensitive | Moisture Sensitive |
| CAS DataBase Reference | 1722-26-5(CAS DataBase Reference) |
| NIST Chemistry Reference | Triethylamineborane(1722-26-5) |
| EPA Substance Registry System | Boron, (N,N-diethylethanamine)trihydro-, (T-4)- (1722-26-5) |
Safety information for Borane-triethylamine complex
| Signal word | Danger |
| Pictogram(s) |
 Flame Flammables GHS02  Corrosion Corrosives GHS05  Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H225:Flammable liquids H314:Skin corrosion/irritation |
| Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P280:Wear protective gloves/protective clothing/eye protection/face protection. P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for Borane-triethylamine complex
| InChIKey | ONRDAGWFOUZNLV-UHFFFAOYSA-N |
Borane-triethylamine complex manufacturer
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