2'-Methoxycinnamaldehyde
Synonym(s):o-Methoxycinnamaldehyde
- CAS NO.:1504-74-1
- Empirical Formula: C10H10O2
- Molecular Weight: 162.19
- MDL number: MFCD00007001
- EINECS: 216-131-3
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-12-18 14:08:52
What is 2'-Methoxycinnamaldehyde?
Description
o-Methoxycinnamaldehyde has a sweet, warm, spicy-floral odor with fruity undertones. It has a sweet, spicy, warm flavor, somewhat pungent above 200 - 300 ppm. It is formed after a long contact period between salicylaldehyde and acetaldehyde in diluted alkaline solution; it can be formed by condensation of salicylaldehyde methylether with acetaldehyde under alkaline conditions; from the corresponding oxime.
Chemical properties
o-Methoxycinnamaldehyde has a sweet, warm, spicy-floral odor with fruity undernotes. It has a sweet, spicy, warm flavor and is somewhat pungent above 200 to 300?ppm.
Occurrence
Reported found in cinnamon oil (Cinnamomum cassia Nees ex Bl.) from which it is separated as stearoptene; in cinnamon bark and leaf.
What are the applications of Application
2-Methoxycinnamaldehyde, predominantly trans is A Cinnamomum cassia component
Preparation
It is formed after a long contact period between salicylaldehyde and acetaldehyde in diluted alkaline solution; it may also be formed by condensation of salicylaldehyde methylether with acetaldehyde under alkaline conditions; from the corresponding oxime. It may be isolated and purified from powdered cinnamon.
Definition
ChEBI: Cassiastearoptene is a member of cinnamaldehydes.
Taste threshold values
Taste characteristics at 50 ppm: warm, spicy, cinnamon and clove-like.
General Description
Yellow crystals.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
Aldehydes, such as 2'-Methoxycinnamaldehyde, are frequently involved in self-condensation or polymerization reactions. These reactions are exothermic; they are often catalyzed by acid. Aldehydes are readily oxidized to give carboxylic acids. Flammable and/or toxic gases are generated by the combination of aldehydes with azo, diazo compounds, dithiocarbamates, nitrides, and strong reducing agents. Aldehydes can react with air to give first peroxo acids, and ultimately carboxylic acids. These autoxidation reactions are activated by light, catalyzed by salts of transition metals, and are autocatalytic (catalyzed by the products of the reaction). The addition of stabilizers (antioxidants) to shipments of aldehydes retards autoxidation.
Fire Hazard
2'-Methoxycinnamaldehyde is flammable.
Properties of 2'-Methoxycinnamaldehyde
Melting point: | 44-48 °C(lit.) |
Boiling point: | 160-161 °C12 mm Hg(lit.) |
Density | 1.0281 (rough estimate) |
refractive index | 1.6000 (estimate) |
FEMA | 3181 | O-METHOXYCINNAMALDEHYDE |
Flash point: | >230 °F |
storage temp. | 2-8°C |
solubility | Chloroform (Slightly), DMSO (Sparingly) |
form | Solid |
color | Yellow |
Odor | at 100.00 %. sweet cinnamon cassia oily woody paper |
JECFA Number | 688 |
CAS DataBase Reference | 1504-74-1(CAS DataBase Reference) |
NIST Chemistry Reference | 2-Propenal, 3-(2-methoxyphenyl)-(1504-74-1) |
EPA Substance Registry System | o-Methoxycinnamaldehyde (1504-74-1) |
Safety information for 2'-Methoxycinnamaldehyde
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for 2'-Methoxycinnamaldehyde
InChIKey | KKVZAVRSVHUSPL-GQCTYLIASA-N |
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