α-Methylcinnamaldehyde
- CAS NO.:101-39-3
- Empirical Formula: C10H10O
- Molecular Weight: 146.19
- MDL number: MFCD00006976
- EINECS: 202-938-8
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-11-13 18:13:23
What is α-Methylcinnamaldehyde?
Description
α-Methylcinnamaldehyde has a characteristic cinnamon-type odor with a soft, spicy flavor. May be synthesized by condensing benzaldehyde with propionic aldehyde in the presence of a 1% caustic soda solution; also by the controlled hydrogenation of α-methylcinnamic aldehyde.
Chemical properties
α-Methylcinnamaldehyde has a characteristic cinnamon-type odor and a soft, spicy flavor.
Chemical properties
yellow liquid
Occurrence
Reported found in peppermint oil, sherry and mint
The Uses of α-Methylcinnamaldehyde
alpha-Methyl-trans-cinnamaldehyde is a compound with antifungal activity for proteomics research use.
Preparation
By condensing benzaldehyde with propionic aldehyde in the presence of a 1% caustic soda solution; also by the controlled hydrogenation of α-methylcinnamic aldehyde
What are the applications of Application
α-Methyl-trans-cinnamaldehyde is α-Methyl-trans-cinnamaldehyde has antifungal activity. It is self coupled and complexed with Co(II) and Ni(II) to synthesize ligand and complexes.
Taste threshold values
Taste characteristics at 30 ppm: spice, cinnamon, sweet, woody with a slight pungent and hot bite
Synthesis Reference(s)
The Journal of Organic Chemistry, 55, p. 2878, 1990 DOI: 10.1021/jo00296a059
Tetrahedron Letters, 28, p. 1263, 1987 DOI: 10.1016/S0040-4039(00)95341-3
General Description
Clear yellow liquid.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
alpha-Methylcinnamaldehyde is incompatible with strong oxidizing agents and strong bases.
Fire Hazard
alpha-Methylcinnamaldehyde is combustible.
Biochem/physiol Actions
α-Methyl trans cinnamaldehyde has antifungal activity. It is self coupled and complexed with Co(II) and Ni(II) to synthesize ligand and complexes.
Safety Profile
Moderately toxic by ingestion. A skin irritant. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.
Properties of α-Methylcinnamaldehyde
Boiling point: | 148-149 °C27 mm Hg(lit.) |
Density | 1.047 g/mL at 25 °C(lit.) |
refractive index | n |
FEMA | 2697 | ALPHA-METHYLCINNAMALDEHYDE |
Flash point: | 175 °F |
storage temp. | Inert atmosphere,2-8°C |
solubility | Chloroform, Methanol (Slightly) |
form | Oil |
color | Colourless |
Odor | at 100.00 %. sweet cinnamon spicy cassia |
Water Solubility | <0.1 g/100 mL at 21 ºC |
Sensitive | Air Sensitive |
JECFA Number | 683 |
BRN | 507514 |
Stability: | Stable. Combustible. Incompatible with strong oxidizing agents, strong bases. |
CAS DataBase Reference | 101-39-3(CAS DataBase Reference) |
NIST Chemistry Reference | 2-Propenal, 2-methyl-3-phenyl-(101-39-3) |
EPA Substance Registry System | .alpha.-Methylcinnamaldehyde (101-39-3) |
Safety information for α-Methylcinnamaldehyde
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H227:Flammable liquids H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P280:Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P405:Store locked up. |
Computed Descriptors for α-Methylcinnamaldehyde
InChIKey | VLUMOWNVWOXZAU-VQHVLOKHSA-N |
Abamectin manufacturer
HJ AROCHEM
Mruchem
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