2-Iodoxybenzoic acid
Synonym(s):SIBX;Stabilized IBX
- CAS NO.：61717-82-6
- Empirical Formula: C7H5IO4
- Molecular Weight: 280.02
- MDL number: MFCD02912492
- EINECS: 629-407-7
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-08-17 21:30:02
What is 2-Iodoxybenzoic acid?
Description
2-Iodoxybenzoic acid (IBX) is a reagent typically used to oxidize alcohols to aldehydes or ketones. IBX is not soluble in many common organic solvents. Dess-Martin Periodinane is closely related to IBX and has the major benefit of being much more soluble in various solvents. IBX is considered to possibly be shock sensitive.
Chemical properties
White to off-white powder, prills or agglomerates
The Uses of 2-Iodoxybenzoic acid
2-Iodoxybenzoic Acid is used in the oxidation of alcohols in organic synthesis. It is also frequently used in the preparation of Dess-Martin periodinane.
The Uses of 2-Iodoxybenzoic acid
Stabilized 2-Iodoxybenzoic Acid (SIBX)
What are the applications of Application
2-Iodoxybenzoic acid is a stabilized, non-explosive version of IBX which maintains selectivity and reactivity
Definition
ChEBI: A benziodoxole compound having hydroxy and oxo substituents at the 1-position and an oxo substituent at the 3-position.
Synthesis Reference(s)
The Journal of Organic Chemistry, 48, p. 4155, 1983 DOI: 10.1021/jo00170a070
Properties of 2-Iodoxybenzoic acid
| Melting point: | 280 °C |
| storage temp. | under inert gas (nitrogen or Argon) at 2–8 °C |
| solubility | DMSO (Very Slightly, Heated) |
| form | powder to crystal |
| color | White to Almost white |
| Merck | 14,5048 |
| CAS DataBase Reference | 61717-82-6(CAS DataBase Reference) |
Safety information for 2-Iodoxybenzoic acid
| Signal word | Danger |
| Pictogram(s) |
 Corrosion Corrosives GHS05  Exclamation Mark Irritant GHS07  Health Hazard GHS08 |
| GHS Hazard Statements |
H314:Skin corrosion/irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation H372:Specific target organ toxicity, repeated exposure |
| Precautionary Statement Codes |
P260:Do not breathe dust/fume/gas/mist/vapours/spray. P270:Do not eat, drink or smoke when using this product. P280:Wear protective gloves/protective clothing/eye protection/face protection. P314:Get medical advice/attention if you feel unwell. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for 2-Iodoxybenzoic acid
| InChIKey | CQMJEZQEVXQEJB-UHFFFAOYSA-N |
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