1,6-Dibromohexane
Synonym(s):1,6-Dibromohexane;Hexamethylene bromide;Hexamethylene dibromide
- CAS NO.:629-03-8
- Empirical Formula: C6H12Br2
- Molecular Weight: 243.97
- MDL number: MFCD00000272
- EINECS: 211-067-2
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-10-25 16:21:11
What is 1,6-Dibromohexane ?
Chemical properties
colourless or pale yellow liquid. soluble in ethanol, ether, benzene and chloroform, insoluble in water. It is used in the synthesis of the hypotensive drug hexamethonium bromide.
The Uses of 1,6-Dibromohexane
1,6-Dibromohexane is used as a reagent in the synthesis of novel benzo[b]xanthone derivatives which have a potential antitumor activity. It is also used as a cross-linker for the cross-linking of glycuronans.
The Uses of 1,6-Dibromohexane
1,6-Dibromohexane is generally used to introduce C6 spacer in the molecular architecture. Some of the examples are:
Synthesis of solvent processable and conductive polyfluorene ionomers for alkaline fuel cell applications.
Synthesis of cross-linkable regioregular poly(3-(5-hexenyl)thiophene) (P3HNT) for stabilizing the film morphology in polymer photovoltaic cells.
Synthesis of pyrrolo-tetrathiafulvalene molecular bridge (6PTTF6) to study redox switching behavior of single molecules.
Synthesis of water-soluble thermoresponsive polylactides.
Preparation
1,6-Dibromohexane is synthesized from hexanediol by bromination.
Properties of 1,6-Dibromohexane
Melting point: | -2-2.5 °C (lit.) |
Boiling point: | 243 °C (lit.) |
Density | 1.586 g/mL at 25 °C (lit.) |
vapor pressure | <1 hPa (20 °C) |
refractive index | n |
Flash point: | 110 °C |
storage temp. | Store below +30°C. |
solubility | soluble in Chloroform, Ethyl Acetate |
form | Liquid |
color | colorless to brownish-yellow |
Water Solubility | insoluble |
BRN | 1236322 |
Dielectric constant | 8.8900000000000006 |
Stability: | Stable. Incompatible with strong oxidizing agents. |
CAS DataBase Reference | 629-03-8(CAS DataBase Reference) |
NIST Chemistry Reference | Hexane, 1,6-dibromo-(629-03-8) |
EPA Substance Registry System | Hexane, 1,6-dibromo- (629-03-8) |
Safety information for 1,6-Dibromohexane
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 Environment GHS09 |
GHS Hazard Statements |
H302:Acute toxicity,oral H317:Sensitisation, Skin H411:Hazardous to the aquatic environment, long-term hazard |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P273:Avoid release to the environment. P280:Wear protective gloves/protective clothing/eye protection/face protection. P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P302+P352:IF ON SKIN: wash with plenty of soap and water. |
Computed Descriptors for 1,6-Dibromohexane
InChIKey | SGRHVVLXEBNBDV-UHFFFAOYSA-N |
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