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HomeProduct name list1,6-Dibromohexane

1,6-Dibromohexane

Synonym(s):1,6-Dibromohexane;Hexamethylene bromide;Hexamethylene dibromide

  • CAS NO.:629-03-8
  • Empirical Formula: C6H12Br2
  • Molecular Weight: 243.97
  • MDL number: MFCD00000272
  • EINECS: 211-067-2
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-10-25 16:21:11
1,6-Dibromohexane  Structural

What is 1,6-Dibromohexane ?

Chemical properties

colourless or pale yellow liquid. soluble in ethanol, ether, benzene and chloroform, insoluble in water. It is used in the synthesis of the hypotensive drug hexamethonium bromide.

The Uses of 1,6-Dibromohexane

1,6-Dibromohexane is used as a reagent in the synthesis of novel benzo[b]xanthone derivatives which have a potential antitumor activity. It is also used as a cross-linker for the cross-linking of glycuronans.

The Uses of 1,6-Dibromohexane

1,6-Dibromohexane is generally used to introduce C6 spacer in the molecular architecture. Some of the examples are:
Synthesis of solvent processable and conductive polyfluorene ionomers for alkaline fuel cell applications.
Synthesis of cross-linkable regioregular poly(3-(5-hexenyl)thiophene) (P3HNT) for stabilizing the film morphology in polymer photovoltaic cells.
Synthesis of pyrrolo-tetrathiafulvalene molecular bridge (6PTTF6) to study redox switching behavior of single molecules.
Synthesis of water-soluble thermoresponsive polylactides.

Preparation

1,6-Dibromohexane is synthesized from hexanediol by bromination.

Properties of 1,6-Dibromohexane

Melting point: -2-2.5 °C (lit.)
Boiling point: 243 °C (lit.)
Density  1.586 g/mL at 25 °C (lit.)
vapor pressure  <1 hPa (20 °C)
refractive index  n20/D 1.507(lit.)
Flash point: 110 °C
storage temp.  Store below +30°C.
solubility  soluble in Chloroform, Ethyl Acetate
form  Liquid
color  colorless to brownish-yellow
Water Solubility  insoluble
BRN  1236322
Dielectric constant 8.8900000000000006
Stability: Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference 629-03-8(CAS DataBase Reference)
NIST Chemistry Reference Hexane, 1,6-dibromo-(629-03-8)
EPA Substance Registry System Hexane, 1,6-dibromo- (629-03-8)

Safety information for 1,6-Dibromohexane

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
ghs
Environment
GHS09
GHS Hazard Statements H302:Acute toxicity,oral
H317:Sensitisation, Skin
H411:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P273:Avoid release to the environment.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352:IF ON SKIN: wash with plenty of soap and water.

Computed Descriptors for 1,6-Dibromohexane

InChIKey SGRHVVLXEBNBDV-UHFFFAOYSA-N

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