1-Bromohexane
Synonym(s):1-Bromohexane;Bromohexane;Hexyl bromide
- CAS NO.:111-25-1
- Empirical Formula: C6H13Br
- Molecular Weight: 165.07
- MDL number: MFCD00000271
- EINECS: 203-850-2
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-12-18 14:08:52
What is 1-Bromohexane?
Chemical properties
1-Bromohexane is a colourless liquid organohalide. It is a solvent that is frequently used in grignard reactions. It is also used as Intermediate, for introduction of hexyl group.
The Uses of 1-Bromohexane
1-Bromohexane is utilized in the preparation of pharmaceuticals and organic chemicals. It is involved in Grignard reactions as an alkylating agent and in the synthesis of bromo-cyclic compounds.
What are the applications of Application
1-Bromohexane is a very useful synthetic intermediate,it can be used to react with Mg to prepare Grignard reagents which play an important role in formation of carbon-carbon bond.
Synthesis Reference(s)
Chemistry Letters, 7, p. 833, 1978
Synthetic Communications, 6, p. 21, 1976 DOI: 10.1080/00397917608062128
Tetrahedron, 40, p. 641, 1984 DOI: 10.1016/S0040-4020(01)91092-0
Purification Methods
Shake the bromide with H2SO4, wash with water, dry (K2CO3) and fractionally distil. [Beilstein 1 IV 352.]
Properties of 1-Bromohexane
Melting point: | −85 °C(lit.) |
Boiling point: | 154-158 °C(lit.) |
Density | 1.176 g/mL at 25 °C(lit.) |
vapor density | 5.7 (vs air) |
vapor pressure | <10 mm Hg ( 20 °C) |
refractive index | n |
Flash point: | 135 °F |
storage temp. | Store below +30°C. |
solubility | <1g/l |
form | Liquid |
color | Clear |
Water Solubility | Immiscible with water. |
BRN | 1731290 |
Dielectric constant | 5.8(24℃) |
Stability: | Stable. Incompatible with strong oxidizing agents, strong bases. Combustible. |
CAS DataBase Reference | 111-25-1(CAS DataBase Reference) |
NIST Chemistry Reference | Hexane, 1-bromo-(111-25-1) |
EPA Substance Registry System | Hexane, 1-bromo- (111-25-1) |
Safety information for 1-Bromohexane
Signal word | Warning |
Pictogram(s) |
Flame Flammables GHS02 Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H226:Flammable liquids H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P233:Keep container tightly closed. P240:Ground/bond container and receiving equipment. P241:Use explosion-proof electrical/ventilating/lighting/…/equipment. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for 1-Bromohexane
InChIKey | MNDIARAMWBIKFW-UHFFFAOYSA-N |
1-Bromohexane manufacturer
Bhavika Chemicals Corporation
Delta Finochem Pvt Ltd
Best Value Chem Pvt Ltd
New Products
Tert-butyl bis(2-chloroethyl)carbamate 4-Methylphenylacetic acid N-Boc-D-alaninol N-BOC-D/L-ALANINOL N-octanoyl benzotriazole 3-Morpholino-1-(4-nitrophenyl)-5,6-dihydropyridin- 2(1H)-one Furan-2,5-Dicarboxylic Acid DIETHYL AMINOMALONATE HYDROCHLORIDE 1,1’-CARBONYLDIIMIDAZOLE R-2-BENZYLOXY PROPIONIC ACID 1,1’-CARBONYLDI (1,2-4 TRIAZOLE) N-METHYL INDAZOLE-3-CARBOXYLIC ACID (2-Hydroxyphenyl)acetonitrile 4-Bromopyrazole 5-BROMO-2CYANO PYRIDINE 5,6-Dimethoxyindanone 5-broMo-2-chloro-N-cyclopentylpyriMidin-4-aMine 2-(Cyanocyclohexyl)acetic acid 4-methoxy-3,5-dinitropyridine 1-(4-(aminomethyl)benzyl)urea hydrochloride 2-aminopropyl benzoate hydrochloride diethyl 2-(2-((tertbutoxycarbonyl)amino) ethyl)malonate tert-butyl 4- (ureidomethyl)benzylcarbamate Ethyl-2-chloro((4-methoxyphenyl)hydrazono)acetateRelated products of tetrahydrofuran
You may like
-
Hexyl Bromide / 1 Bromohexane 111-25-1 99%View Details
111-25-1 -
1-Bromohexane 99%View Details
-
1-Bromohexane 98%View Details
111-25-1 -
111-25-1 98%View Details
111-25-1 -
1-Bromohexane, 98% CAS 111-25-1View Details
111-25-1 -
1-Bromohexane CAS 111-25-1View Details
111-25-1 -
1-Bromohexane CAS 111-25-1View Details
111-25-1 -
1-BROMOHEXANE For Synthesis CAS 111-25-1View Details
111-25-1