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HomeProduct name listZirconyl chloride octahydrate

Zirconyl chloride octahydrate

Synonym(s):Zirconium(IV) oxide chloride;Zirconium(IV) oxide chloride octahydrate;Zirconium(IV) oxychloride octahydrate;Zirconyl chloride;Zirconyl chloride octahydrate

  • CAS NO.:13520-92-8
  • Empirical Formula: Cl2H2O2Zr
  • Molecular Weight: 322.25
  • MDL number: MFCD00149898
  • EINECS: 603-909-6
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-08-08 18:06:34
Zirconyl chloride octahydrate Structural

What is Zirconyl chloride octahydrate?

Chemical properties

solid

The Uses of Zirconyl chloride octahydrate

Zirconium dichloride oxide is utilized as a precursor to prepare other zirconium compounds. It is employed in acid dyes, pigment toners and antiperspirants. It finds application as a rubber additive and a fiber treatment agent. It is also used in paint drying, refractories, ceramics and glaze.

What are the applications of Application

Zirconyl chloride octahydrate is a building block for a new series of mixed zirconium phosphonates

General Description

This product is used as a potential green catalyst.

Purification Methods

Recrystallise the chloride several times from water [Ferragina et al. J Chem Soc, Dalton Trans 265 1986]. Recrystallisation from 8M HCl gives the octahydrate as white needles on concentrating. It is also formed by hydrolysing ZrCl4 with water. After one recrystallisation from H2O, 99+% grade zirconyl chloride had Ag, Al, As, Cd, Cu, Hf, Mg, Na, Sc and V at 20, 1.8, 0.6, 0.6, 0.4, 8.4, 0.4, 2.4, 80 and 3 ppm, respectively. (See above.) METAL-ORGANIC COMPOUNDS This section contains metal-organic compounds as well as ammonium and metal salts of organic acids. (For Introduction see p 445.)

Properties of Zirconyl chloride octahydrate

Melting point: 400°C (dec.)
Boiling point: 210°C
Density  1.91
storage temp.  Store at +15°C to +25°C.
solubility  H2O: soluble
form  Crystalline Powder
color  White to light yellow
Specific Gravity 1.91
PH 1 (50g/l, H2O, 20℃)
Odor Odorless
Water Solubility  SOLUBLE
Sensitive  Hygroscopic
Merck  14,10184
Exposure limits ACGIH: TWA 5 mg/m3; STEL 10 mg/m3
NIOSH: IDLH 25 mg/m3; TWA 5 mg/m3; STEL 10 mg/m3
Stability: Stable, but may be moisture sensitive. Incompatible with strong oxidizing agents.
CAS DataBase Reference 13520-92-8(CAS DataBase Reference)

Safety information for Zirconyl chloride octahydrate

Signal word Danger
Pictogram(s)
ghs
Corrosion
Corrosives
GHS05
GHS Hazard Statements H314:Skin corrosion/irritation
Precautionary Statement Codes P260:Do not breathe dust/fume/gas/mist/vapours/spray.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Zirconyl chloride octahydrate

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