Zirconyl chloride octahydrate
Synonym(s):Zirconium(IV) oxide chloride;Zirconium(IV) oxide chloride octahydrate;Zirconium(IV) oxychloride octahydrate;Zirconyl chloride;Zirconyl chloride octahydrate
- CAS NO.:13520-92-8
- Empirical Formula: Cl2H2O2Zr
- Molecular Weight: 322.25
- MDL number: MFCD00149898
- EINECS: 603-909-6
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-08-08 18:06:34
What is Zirconyl chloride octahydrate?
Chemical properties
solid
The Uses of Zirconyl chloride octahydrate
Zirconium dichloride oxide is utilized as a precursor to prepare other zirconium compounds. It is employed in acid dyes, pigment toners and antiperspirants. It finds application as a rubber additive and a fiber treatment agent. It is also used in paint drying, refractories, ceramics and glaze.
What are the applications of Application
Zirconyl chloride octahydrate is a building block for a new series of mixed zirconium phosphonates
General Description
This product is used as a potential green catalyst.
Purification Methods
Recrystallise the chloride several times from water [Ferragina et al. J Chem Soc, Dalton Trans 265 1986]. Recrystallisation from 8M HCl gives the octahydrate as white needles on concentrating. It is also formed by hydrolysing ZrCl4 with water. After one recrystallisation from H2O, 99+% grade zirconyl chloride had Ag, Al, As, Cd, Cu, Hf, Mg, Na, Sc and V at 20, 1.8, 0.6, 0.6, 0.4, 8.4, 0.4, 2.4, 80 and 3 ppm, respectively. (See above.) METAL-ORGANIC COMPOUNDS This section contains metal-organic compounds as well as ammonium and metal salts of organic acids. (For Introduction see p 445.)
Properties of Zirconyl chloride octahydrate
Melting point: | 400°C (dec.) |
Boiling point: | 210°C |
Density | 1.91 |
storage temp. | Store at +15°C to +25°C. |
solubility | H2O: soluble |
form | Crystalline Powder |
color | White to light yellow |
Specific Gravity | 1.91 |
PH | 1 (50g/l, H2O, 20℃) |
Odor | Odorless |
Water Solubility | SOLUBLE |
Sensitive | Hygroscopic |
Merck | 14,10184 |
Exposure limits | ACGIH: TWA 5 mg/m3; STEL 10 mg/m3 NIOSH: IDLH 25 mg/m3; TWA 5 mg/m3; STEL 10 mg/m3 |
Stability: | Stable, but may be moisture sensitive. Incompatible with strong oxidizing agents. |
CAS DataBase Reference | 13520-92-8(CAS DataBase Reference) |
Safety information for Zirconyl chloride octahydrate
Signal word | Danger |
Pictogram(s) |
Corrosion Corrosives GHS05 |
GHS Hazard Statements |
H314:Skin corrosion/irritation |
Precautionary Statement Codes |
P260:Do not breathe dust/fume/gas/mist/vapours/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for Zirconyl chloride octahydrate
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