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HomeProduct name listPhenyl phosphine

Phenyl phosphine

  • CAS NO.:638-21-1
  • Empirical Formula: C6H7P
  • Molecular Weight: 110.09
  • MDL number: MFCD00002094
  • EINECS: 211-325-4
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-08-17 18:11:45
Phenyl phosphine Structural

What is Phenyl phosphine?

Chemical properties

Phenylphosphine is a clear, colorless liquid. Foul odor.

The Uses of Phenyl phosphine

suzuki reaction

The Uses of Phenyl phosphine

Exposure to phenylphosphine may occur when phenylphosphinates (used as catalysts and antioxidants) are heated above 200°C, yielding phenylphosphonic acid derivatives and phenylphosphine.

The Uses of Phenyl phosphine

It is mainly used as a precursor to other organophosphorus compounds. It can function as a?ligand?in coordination chemistry. Phenylphosphine also have uses in polymer synthesis.

General Description

Clear colorless liquid.

Air & Water Reactions

Pyrophoric in air. Insoluble in water. Slowly generates flammable or noxious gases in contact with water.

Reactivity Profile

Phenyl phosphine is a reducing agent. They slowly generate flammable or noxious gases in contact with water. Phosphides react quickly upon contact with moisture or acids to give the very toxic gas phosphine; phosphides also can react vigorously with oxidizing materials. In general, materials in this group are incompatible with oxidizers such as atmospheric oxygen. They are violently incompatible with acids, particularly oxidizing acids.

Health Hazard

Phenylphosphine is a respiratory and skin irritant; multiple exposures in rodents causes hematologic changes and testicular degeneration in males.

Fire Hazard

Flash point data are not available for Phenyl phosphine, but Phenyl phosphine is probably combustible.

Safety Profile

Poison by inhalation. Igmtes spontaneously in air. When heated to decomposition it emits toxic fumes of POx. See also PHOSPHINE.

Potential Exposure

Polyphosphinate is used as an intermediate or a chemical reagent. Polyphosphinate compounds are used as catalysts and antioxidants disproportionate, when heated to give phosphonic acid derivatives plus PF.

Shipping

UN2845 Pyrophoric liquids, organic, n.o.s Hazard Class: 4.2, Labels: 4.2-Spontaneously combustible material. Technical Name Required. Note: this chemical is also a strong reducing agent.

Incompatibilities

A strong reducing agent. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Water reactive; spontaneously combustible in high concentrations in moist air. Potential exposure to gaseous phenylphosphine and phosphorus oxides when heated above 200C. Organophosphates are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrideds and active metals. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.

Properties of Phenyl phosphine

Melting point: 148-151 °C
Boiling point: 160°C
Density  1.001
vapor density  3.79 (vs air)
vapor pressure  760 mmHg ( 160 °C)
refractive index  1.578
Flash point: -20°F
storage temp.  -20°C
form  liquid
color  colorless
Water Solubility  Insoluble in water.
Sensitive  Air & Moisture Sensitive
BRN  741946
Exposure limits ACGIH: Ceiling 0.05 ppm
NIOSH: Ceiling 0.05 ppm(0.25 mg/m3)
CAS DataBase Reference 638-21-1(CAS DataBase Reference)
NIST Chemistry Reference Phenylphosphine(638-21-1)
EPA Substance Registry System Phenylphosphine (638-21-1)

Safety information for Phenyl phosphine

Signal word Danger
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Exclamation Mark
Irritant
GHS07
ghs
Health Hazard
GHS08
ghs
Environment
GHS09
GHS Hazard Statements H225:Flammable liquids
H302:Acute toxicity,oral
H304:Aspiration hazard
H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H336:Specific target organ toxicity,single exposure; Narcotic effects
H411:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P273:Avoid release to the environment.
P331:Do NOT induce vomiting.
P301+P310:IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Phenyl phosphine

InChIKey RPGWZZNNEUHDAQ-UHFFFAOYSA-N

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