CHEMICAL AND PHYSICAL PROPERTIES
Physical Description | Phenyl phosphine is a clear colorless liquid. (NTP, 1992) |
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Color/Form | Clear, colorless liquid |
Odor | Foul odor |
Boiling Point | 320 to 322 °F at 760 mmHg (NTP, 1992) |
Solubility | less than 1 mg/mL at 70 °F (NTP, 1992) |
Density | 1.001 at 59 °F (NTP, 1992) - Denser than water; will sink |
Vapor Density | 3.79 (NTP, 1992) - Heavier than air; will sink (Relative to Air) |
Vapor Pressure | 2.45 [mmHg] |
LogP | log Kow = 1.49 /Estimated/ |
Henry's Law Constant | Henry's Law constant = 2.38X10-4 atm-cu m/mol @ 25 °C /Estimated/ |
Decomposition | The substance decomposes on heating producing toxic fumes including phosphorous oxides and phosphine. |
Odor Threshold | Concentrations of 0.57 ppm (2.6 mg/cu m) were readily detected by an odor panel; the odor was experienced as obnoxious. As lower concentration were not evaluated, an odor threshold was not established. |
Other Experimental Properties | Spontaneously combustible in high concentrations in air. Potential exposure to gaseous phenylphosphine when polyphosphinates are heated above 200 °C |
Chemical Classes | Other Classes -> Phosphorus Compounds |
SAFETY INFORMATION
Signal word | Danger |
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Pictogram(s) |
Flame Flammables GHS02 Exclamation Mark Irritant GHS07 Health Hazard GHS08 Environment GHS09 |
GHS Hazard Statements |
H225:Flammable liquids H302:Acute toxicity,oral H304:Aspiration hazard H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H336:Specific target organ toxicity,single exposure; Narcotic effects H411:Hazardous to the aquatic environment, long-term hazard |
Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P273:Avoid release to the environment. P331:Do NOT induce vomiting. P301+P310:IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
COMPUTED DESCRIPTORS
Molecular Weight | 110.09 g/mol |
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XLogP3 | 1.8 |
Hydrogen Bond Donor Count | 0 |
Hydrogen Bond Acceptor Count | 0 |
Rotatable Bond Count | 0 |
Exact Mass | 110.028537221 g/mol |
Monoisotopic Mass | 110.028537221 g/mol |
Topological Polar Surface Area | 0 Ų |
Heavy Atom Count | 7 |
Formal Charge | 0 |
Complexity | 46.1 |
Isotope Atom Count | 0 |
Defined Atom Stereocenter Count | 0 |
Undefined Atom Stereocenter Count | 0 |
Defined Bond Stereocenter Count | 0 |
Undefined Bond Stereocenter Count | 0 |
Covalently-Bonded Unit Count | 1 |
Compound Is Canonicalized | Yes |
PRODUCT INTRODUCTION
description
Phenyl phosphine is a clear colorless liquid. (NTP, 1992)