NICKEL BROMATE

CAS NO.：13462-88-9
Empirical Formula: Br2Ni
Molecular Weight: 218.5
MDL number: MFCD00049991
EINECS: 236-665-0
SAFETY DATA SHEET (SDS)
Update Date: 2024-11-15 19:19:13

What is NICKEL BROMATE?

Chemical properties

Brownish powder

The Uses of NICKEL BROMATE

Nickel(II) Bromide, is used as a source of bromide ion. It is also an important raw material used in various chemical synthesis and also as a catalyst in cross-coupling reactions.

General Description

Yellowish-green odorless solid. Sinks in and mixes with water.

Air & Water Reactions

Deliquescent. Soluble in water.

Reactivity Profile

NICKEL BROMATE is a yellow, crystalline material, mildly toxic, carcinogenic. On contact with strong acids or acid fumes NICKEL BROMATE produces highly toxic and corrosive hydrogen bromide gas. When heated to decomposition NICKEL BROMATE emits toxic bromide fumes. [M. K.]

Health Hazard

Inhalation of dust causes irritation of nose and throat. Ingestion causes vomiting; if large amount is swallowed and not thrown up, it can cause drowsiness and other symptoms of bromide poisoning. Dust irritates eyes and may cause dermatitis in contact with skin.

Fire Hazard

Special Hazards of Combustion Products: Irritating hydrogen bromide vapors may form in fire.

Purification Methods

Crystallise it from dilute HBr (0.5mL/g) by partial evaporation in a desiccator. The anhydrous salt is yellow, but the trihydrate is green.

Properties of NICKEL BROMATE

Melting point:	963 °C (lit.)
Density	5.098 g/mL at 25 °C (lit.)
storage temp.	Inert atmosphere,Room Temperature
solubility	H2O: slightly soluble(lit.)
form	powder
color	Brown
Specific Gravity	5.098
Water Solubility	Soluble in water, alcohol and ether.
Sensitive	Hygroscopic
Merck	14,6502
Exposure limits	ACGIH: TWA 0.1 mg/m3 NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
Stability:	Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference	13462-88-9(CAS DataBase Reference)
EPA Substance Registry System	Nickel(II) bromide (13462-88-9)

Safety information for NICKEL BROMATE

Signal word	Danger
Pictogram(s)	Health Hazard GHS08 Environment GHS09
GHS Hazard Statements	H317:Sensitisation, Skin H334:Sensitisation, respiratory H341:Germ cell mutagenicity H350:Carcinogenicity H360:Reproductive toxicity H372:Specific target organ toxicity, repeated exposure H410:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes	P201:Obtain special instructions before use. P273:Avoid release to the environment. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P308+P313:IF exposed or concerned: Get medical advice/attention.