Nickel bis(sulphamidate)

CAS NO.：13770-89-3
Empirical Formula: H3NNiO3S
Molecular Weight: 155.78
MDL number: MFCD00137261
EINECS: 237-396-1
SAFETY DATA SHEET (SDS)
Update Date: 2024-08-04 20:11:12

What is Nickel bis(sulphamidate)?

Chemical properties

blue-green crystals

The Uses of Nickel bis(sulphamidate)

Nickel sulfamate is used as an electrolyte in nickel electroplating systems.

The Uses of Nickel bis(sulphamidate)

Nickel plating Nickel(II) sulfamate is used for electroplating and as a surface treating agent. It finds application in metal coloring and casting.

Preparation

Nickel sulfamate is prepared by heating an aqueous solution of sulfamic acid, H₂NSO₃H, with fine nickel powder or black nickel oxide under controlled conditions:2H₂NSO₃H + NiO → Ni(SO₃NH₂)₂ + H₂O
At ordinary temperatures, sulfamic acid hydrolyzes slowly forming ammonium bisulfite. However, when heated it hydrolyzes rapidly forming sulfuric acid. Therefore nickel sulfamate should be prepared rapidly before any sulfamic acid hydrolysis occurs due to longer contact time with water.
Nickel sulfamate also can be prepared by the action of sodium sulfamate on nickel carbonate: 2H₂NSO₃Na + NiCO₃ → Ni(SO₃NH₂)₂ + Na₂CO₃
Nickel sulfamate is usually not isolated from its product mixtures. The product solution is sold for commercial applications.

Flammability and Explosibility

Non flammable

Safety Profile

Confirmed human carcinogen. Poison by intraperitoneal route. When heated to decomposition it emits very toxic fumes of SOx and NOx. See also NICKEL COMPOUNDS.

Properties of Nickel bis(sulphamidate)

Density	2.25[at 20℃]
RTECS	QR9275000
form	Liquid
color	Green
Water Solubility	Soluble in water.
Exposure limits	ACGIH: TWA 0.1 mg/m3 NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
Stability:	Stable. Incompatible with oxidizing agents.
CAS DataBase Reference	13770-89-3(CAS DataBase Reference)
EPA Substance Registry System	Sulfamic acid, nickel(2+) salt (2:1) (13770-89-3)

Safety information for Nickel bis(sulphamidate)

Signal word	Danger
Pictogram(s)	Health Hazard GHS08 Environment GHS09
GHS Hazard Statements	H317:Sensitisation, Skin H334:Sensitisation, respiratory H341:Germ cell mutagenicity H350:Carcinogenicity H360:Reproductive toxicity H372:Specific target organ toxicity, repeated exposure H400:Hazardous to the aquatic environment, acute hazard H410:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes	P201:Obtain special instructions before use. P260:Do not breathe dust/fume/gas/mist/vapours/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P284:Wear respiratory protection. P405:Store locked up.