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HomeProduct name listMETHYLTRIOXORHENIUM(VII)

METHYLTRIOXORHENIUM(VII)

Synonym(s):Methylrhenium(VII) trioxide;MTO

  • CAS NO.:70197-13-6
  • Empirical Formula: CH3O3Re
  • Molecular Weight: 249.24
  • MDL number: MFCD00192332
  • EINECS: 677-701-9
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-05-11 17:26:00
METHYLTRIOXORHENIUM(VII) Structural

What is METHYLTRIOXORHENIUM(VII)?

Chemical properties

white to blue-grey crystals

The Uses of METHYLTRIOXORHENIUM(VII)

Methyltrioxorhenium(VII) is used as a catalyst for various transformations such as olefin metathesis. It is associated with hydrogen peroxide and used as an oxidizing agent. It is used to prepare acid or ester from the corresponding terminalalkynes. It is a catalytic oxidant used with urea hydrogen peroxide to prepare nitrones. It reacts with 2-methylnaphthalene to get 2-methyl-1,4-naphthoquinone (Vitamin K3). Further, it catalyzes the reaction with aldehydes and diazoketones to get an alkene. In addition to this, it is used as an effective antioxidant under various conditions.

The Uses of METHYLTRIOXORHENIUM(VII)

Potent catalytic oxidant for converting alkenes to epoxides in a variety of solvents and 2-methylnaphthalene to 2-methyl-1,4-naphthoquinone (Vitamin K3).
Catalytic oxidant used with urea hydrogen peroxide in an efficient conversion of imines to nitrones.
An effective antioxidant under various conditions.

What are the applications of Application

Methyltrioxorhenium(VII) is a catalytic oxidant and antioxidant

Properties of METHYLTRIOXORHENIUM(VII)

Melting point: 111 °C(lit.)
Boiling point: 65°C 0mm
Density  d23 4.21
form  crystal
color  colorless to pale-gray
Water Solubility  Soluble in water.
Sensitive  Moisture & Light Sensitive
Merck  14,6130
BRN  3927932

Safety information for METHYLTRIOXORHENIUM(VII)

Signal word Warning
Pictogram(s)
ghs
Flame Over Circle
Oxidizers
GHS03
GHS Hazard Statements H272:Oxidising liquids;Oxidising solids
Precautionary Statement Codes P220:Keep/Store away from clothing/…/combustible materials.
P221:Take any precaution to avoid mixing with combustibles/…

Computed Descriptors for METHYLTRIOXORHENIUM(VII)

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