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HomeProduct name listMonoperoxyphthalic acid magnesium salt hexahydrate

Monoperoxyphthalic acid magnesium salt hexahydrate

Synonym(s):Magnesium bis(monoperoxyphthalate) hexahydrate;MMPP

  • CAS NO.:84665-66-7
  • Empirical Formula: C16H11MgO11-
  • Molecular Weight: 403.56
  • MDL number: MFCD00149614
  • EINECS: 617-608-2
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-10-24 21:11:45
Monoperoxyphthalic acid magnesium salt hexahydrate Structural

What is Monoperoxyphthalic acid magnesium salt hexahydrate?

Chemical properties

White Granules

The Uses of Monoperoxyphthalic acid magnesium salt hexahydrate

Monoperoxyphthalic acid magnesium salt hexahydrate is used as disinfectant for hard surfaces (hospital, food industrial, institution).

The Uses of Monoperoxyphthalic acid magnesium salt hexahydrate

Reagent for:

  • Trans-diaxial hydroxylation under bismuth(III) triflate catalyst
  • Oxidation rections under mild conditions
  • Epoxidation of unsaturated steroids
  • Synthesis of ring-B oxygenated steroids as anticancer agents

What are the applications of Application

Magnesium monoperoxyphthalate hexahydrate is a mild, general oxidizing agent

General Description

Magnesium monoperoxyphthalate hexahydrate is an organic peroxide used in many oxidation reactions. It exhibits non-deflagrating and non-shock-sensitive properties and also used as a surface disinfectant.

Purification Methods

MMPP is a safer reagent than m-chloroperbenzoic acid for oxidation reactions because it is not as explosive and has advantages of solubility. It is soluble in H2O, low-molecular-weight alcohols, i-PrOH and DMF. The product of reaction, Mg phthalate, is soluble in H2O. It has been used in aqueous phase to oxidise compounds in e.g. CHCl3 and using a phase transfer catalyst, e.g. methyltrioctylammonium chloride [Brougham Synthesis 1015 1987]. The oxidising activity can be checked (as for perbenzoic acid in Silbert et al. Org Synth Coll Vol V 906 1973], and if found to be low it would be best to prepare afresh from phthalic anhydride (1mol), H2O2 (1mol) and MgO at 20-25o to give MMPP. [Hignett, European Pat Appl 27 693 1981, Chem Abstr 95 168810 1981, Beilstein 9 IV 3260.]

Properties of Monoperoxyphthalic acid magnesium salt hexahydrate

Melting point: 93 °C (dec.)(lit.)
storage temp.  Sealed in dry,Room Temperature
solubility  DMSO, Methanol
form  Solid
color  White to Off-White
CAS DataBase Reference 84665-66-7(CAS DataBase Reference)

Safety information for Monoperoxyphthalic acid magnesium salt hexahydrate

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H312:Acute toxicity,dermal
H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Monoperoxyphthalic acid magnesium salt hexahydrate

InChIKey WWOYCMCZTZTIGU-UHFFFAOYSA-L

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