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HomeProduct name listIsopropenyl acetate

Isopropenyl acetate

Synonym(s):1-Methylvinyl acetate;Acetone enol acetate;IPA;Isopropenyl acetate

  • CAS NO.:108-22-5
  • Empirical Formula: C5H8O2
  • Molecular Weight: 100.12
  • MDL number: MFCD00008709
  • EINECS: 203-562-7
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-11-19 20:33:22
Isopropenyl acetate Structural

What is Isopropenyl acetate?

Chemical properties

clear colorless to very slightly yellow liquid

The Uses of Isopropenyl acetate

Iodine in isopropenyl acetate is a unique catalyst for the acetylation of a variety of alcohols, phenols and amines under solvent free conditions. It is used as a solvent for cellulose, plastics, oil and fats. It is also a building block used for various organic synthesis.

The Uses of Isopropenyl acetate

Reagent for acylation of potential enols.

What are the applications of Application

Isopropenyl acetate is a biochemical used for proteomics research

Definition

ChEBI: Isopropenyl acetate is an ester.

Synthesis Reference(s)

Journal of the American Chemical Society, 88, p. 2054, 1966 DOI: 10.1021/ja00961a043

General Description

A clear colorless liquid. Flash point near 60°F. Boiling point near 200°F. Less dense than water. Vapors heavier than air. Used to make other chemicals.

Air & Water Reactions

Highly flammable. Soluble in water.

Reactivity Profile

Isopropenyl acetate is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.

Hazard

Flammable, dangerous fire risk.

Health Hazard

May cause toxic effects if inhaled or absorbed through skin. Inhalation or contact with material may irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Fire Hazard

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. May polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

Flammability and Explosibility

Flammable

Safety Profile

Moderately toxic by ingestion. A skin, eye, and mucous membrane irritant. A very dangerous fire hazard when exposed to heat or flame; can react vigorously with oxidizing materials. To fight fire, use alcohol foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.

Properties of Isopropenyl acetate

Melting point: -93 °C
Boiling point: 94 °C (lit.)
Density  0.922 g/mL at 20 °C 0.909 g/mL at 25 °C (lit.)
vapor pressure  23 hPa (20 °C)
FEMA  4152 | ISOPROPENYL ACETATE
refractive index  n20/D 1.401(lit.)
Flash point: 66 °F
storage temp.  Store below +30°C.
solubility  34g/l
form  Liquid
color  Clear colorless to very slightly yellow
PH 3 (34g/l, H2O, 20℃)
Odor at 100.00 %. ethereal acetic fruity sweet berry grape skin
explosive limit 1.8%(V)
Water Solubility  34 g/L (20 ºC)
JECFA Number 1835
Merck  14,5203
BRN  1280347
CAS DataBase Reference 108-22-5(CAS DataBase Reference)
NIST Chemistry Reference 1-Propen-2-ol, acetate(108-22-5)
EPA Substance Registry System Isopropenyl acetate (108-22-5)

Safety information for Isopropenyl acetate

Signal word Danger
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H225:Flammable liquids
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

Computed Descriptors for Isopropenyl acetate

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