Iridium dioxide
- CAS NO.:12030-49-8
- Empirical Formula: IrO2
- Molecular Weight: 224.22
- MDL number: MFCD00011065
- EINECS: 234-743-9
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-12-18 14:15:30
What is Iridium dioxide?
Description
Iridium, atomic number 77, is a metallic element in the period 6 transition group. It is quite rare and has relatively few compounds, natural or synthetic. Despite its scarcity, it can exist in oxidation states ranging from –3 to +9.
The most common oxide of iridium by far has the +4 oxidation state: iridium(IV) oxide, or IrO2. Ir2O3 [Ir(III)] and IrO4 [Ir(VIII)] are also known. As the image shows, crystalline IrO2 adopts the rutile (TiO2) structure with iridium coordinated to six oxygen atoms.
IrO2 is prepared by heating elemental iridium or IrCl3 in the presence of oxygen. Additional heating causes the oxide to decompose into its elements. Most current IrO2 applications involve its deposition on substrates such as carbon nanotubes.
IrO2 has beneficial properties such as inertness under biological conditions and usefulness in catalysis and electrical devices. Its applications include electrodes for industrial electrolysis and regenerative fuel cells and materials for minimally invasive devices such as stents for treating coronary heart disease.
Chemical properties
BLACK POWDER
The Uses of Iridium dioxide
Iridium(IV) oxide is used in the coating of anode-electrodes for industrial electrolysis in association with other rare oxides. It is also used in microelectrodes for electrophysiology research.
Properties of Iridium dioxide
Melting point: | 1100°C (dec.) |
Density | 11,7 g/cm3 |
storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
solubility | 2 mg/l |
appearance | blue or black crystals or powder |
form | Powder |
color | Black |
Specific Gravity | 11.66 |
Water Solubility | INSOLUBLE |
InChI | InChI=1S/Ir.2O |
CAS DataBase Reference | 12030-49-8(CAS DataBase Reference) |
NIST Chemistry Reference | Iridium dioxide(12030-49-8) |
EPA Substance Registry System | Iridium oxide (IrO2) (12030-49-8) |
Safety information for Iridium dioxide
Signal word | Danger |
Pictogram(s) |
Flame Over Circle Oxidizers GHS03 |
GHS Hazard Statements |
H272:Oxidising liquids;Oxidising solids H413:Hazardous to the aquatic environment, long-term hazard |
Precautionary Statement Codes |
P220:Keep/Store away from clothing/…/combustible materials. P221:Take any precaution to avoid mixing with combustibles/… |
Computed Descriptors for Iridium dioxide
InChIKey | HTXDPTMKBJXEOW-UHFFFAOYSA-N |
SMILES | [Ir](=O)=O |
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