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HomeProduct name listHydrogen fluoride

Hydrogen fluoride

Synonym(s):HF;Hydrofluoric acid solution, Fluoric acid;Hydrogen Fluoride

  • CAS NO.:7664-39-3
  • Empirical Formula: FH
  • Molecular Weight: 20.01
  • MDL number: MFCD00011346
  • EINECS: 231-634-8
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-03-14 15:18:27
Hydrogen fluoride Structural Picture

What is Hydrogen fluoride?

Description

Hydrofluoric acid is a solution of hydrogen fluoride in water. Hydrofluoric acid is highly corrosive inorganic acid. It is utilized widely in the manufacture of ceramics and graphite, in the electropolishing and pickling of metals, in the etching and frosting of glass, in the semiconductor industry as etchant and cleaning agent, in the chemical and oil-refining industries, and in cleaning solutions, laundry powder and pesticides. Hydrofluoric acid is also widely used in the preparation of many useful fluorine compounds, such as Teflon, Freon, fluorocarbons, and many medications such as fluoxetine (Prozac).

Description

Hydrogen fluoride (HF) is an extremely toxic, corrosive gas and liquid. As the lightest of the hydrogen halides, it has a surprisingly high boiling point, higher even than that of hydrogen iodide. The reason is the strong electronegativity of the fluorine atom, which causes hydrogen and fluorine atoms to form hydrogen bonds in the liquid phase.1 The other hydrogen halides are connected by much weaker van der Waals forces.

The Uses of Hydrogen fluoride

Hydrofluoric acid is used as a fluorinatingagent, as a catalyst, and in uranium refining.It is also used for etching glass and forpickling stainless steel. Hydrogen fluoridegas is produced when an inorganic fluoride is distilled with concentrated sulfuricacid.

Background

Hydrogen fluoride (Hydrofluoric acid) is a weak acid that is a precursor to almost all fluorine compounds, including pharmaceuticals such as Fluoxetine (Prozac). It is used as a chemical reagent in several industrial processes such as oil refinery. It is also used as etchant, cleaning agent, and a reagent to dissolve oxides and silicates.

Metabolism

Not Available

Properties of Hydrogen fluoride

Melting point: -35°C
Boiling point: 105°C
Density  1.15 g/mL at 25 °C(lit.)
Flash point: 112°C
storage temp.  Store at +5°C to +30°C.
solubility  miscible
appearance colorless gas
form  Liquid, Double Sub-Boiling Quartz Distillation
color  max. 10
Odor Acrid, irritating odor
Water Solubility  soluble
Sensitive  Hygroscopic

Safety information for Hydrogen fluoride

Signal word Danger
Pictogram(s)

Corrosion
Corrosives
GHS05

Skull and Crossbones
Acute Toxicity
GHS06
GHS Hazard Statements H314:Skin corrosion/irritation
Precautionary Statement Codes P260:Do not breathe dust/fume/gas/mist/vapours/spray.
P270:Do not eat, drink or smoke when using this product.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Hydrogen fluoride

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