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HomeProduct name listBarium hydroxide octahydrate

Barium hydroxide octahydrate

Synonym(s):Barium hydroxide octahydrate;Caustic baryta, Barium oxide hydrate octahydrate

  • CAS NO.:12230-71-6
  • Empirical Formula: BaH4O3
  • Molecular Weight: 189.36
  • MDL number: MFCD00149152
  • EINECS: 602-490-7
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-11-07 13:31:19
Barium hydroxide octahydrate Structural

What is Barium hydroxide octahydrate?

Description

Barium hydroxide is available as colourless or white crystals. It is odourless and soluble in water. It is stable under ordinary conditions of use and storage. It is incompatible with acids, oxidisers, and chlorinated rubber. Barium hydroxide is corrosive to metals such as zinc. Barium hydroxide is very alkaline and rapidly absorbs carbon dioxide from air, becoming completely insoluble in water. Barium hydroxide is used in analytical chemistry for the titration of weak acids. Barium hydroxide is used in organic synthesis as a strong base. Barium hydroxide decomposes to barium oxide when heated to 800°C.

Chemical properties

white crystalline powder

The Uses of Barium hydroxide octahydrate

Barium hydroxide octahydrate is extensively used in the manufacturing of barium salts and barium organic compounds; In manufacture of alkali, glass; in synthetic rubber vulcanization, in corrosion inhibitors, pesticides, sugar industry; boiler scale remedy; refining animal and vegetable oils; softening water. Catalyst in organic synthesis.

The Uses of Barium hydroxide octahydrate

In manufacture of alkali, glass; in synthetic rubber vulcanization, in corrosion inhibitors, pesticides, sugar industry; boiler scale remedy; refining animal and vegetable oils; softening water. Catalyst in organic synthesis.

The Uses of Barium hydroxide octahydrate

Used in manufacture of alkali, glass; in synthetic rubber vulcanization, alkalizing agent in water softening, boiler scale remedy, softening water.Barium hydroxide octahydrate is used in the centromeric heterochromatin banding technique. It acts as a precursor to prepare barium titanate, barium sulfate, barium phosphate and barium sulfide. Further, it is used in analytical chemistry for the titration of weak acids especially organic acids. It is involved in the preparation of cyclopentanone, diacetone alcohol and D-Gulonic gamma-lactone. In addition to this, it finds application in ester hydrolysis such as dimethyl hendecanedioate and decarboxylation of amino acids.

What are the applications of Application

Barium hydroxide octahydrate is an agent used in the centromeric heterochromatin banding technnique

What are the applications of Application

Catalyzes the β-elimination of phosphoserine residues.
Resin stabilizer; manufacture of oil and grease additives; raw material of pigment; sulfate removal agent.

Purification Methods

It crystallises from water (1mL/g) and readily absorbs CO2 from air. It effloresces to the monohydrate. It dehydrates to Ba(OH)2 in dry air at 100o. An aqueous solution (baryta water) absorbs CO2 to form a white precipitate of BaCO3.

Properties of Barium hydroxide octahydrate

Melting point: 78 °C(lit.)
Boiling point: 780°C
Density  2.18
storage temp.  Store at +5°C to +30°C.
solubility  72g/l
form  Solid
color  White
Specific Gravity 2.18
PH Range 12.5 at 50 g/l at 20 °C
PH 14 (H2O, 20℃)(saturated aqueous solution)
Odor Odorless
Water Solubility  56 g/L (15 ºC)
Sensitive  Air Sensitive & Hygroscopic
Merck  14,977
Exposure limits ACGIH: TWA 0.5 mg/m3
NIOSH: IDLH 50 mg/m3; TWA 0.5 mg/m3
Stability: Stable.
CAS DataBase Reference 12230-71-6(CAS DataBase Reference)

Safety information for Barium hydroxide octahydrate

Signal word Danger
Pictogram(s)
ghs
Corrosion
Corrosives
GHS05
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H314:Skin corrosion/irritation
Precautionary Statement Codes P260:Do not breathe dust/fume/gas/mist/vapours/spray.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Barium hydroxide octahydrate

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