1-(2-Pyridylazo)-2-naphthol
Synonym(s):1-(2-Pyridylazo)-2-naphthol (PAN);PAN
- CAS NO.:85-85-8
- Empirical Formula: C15H11N3O
- Molecular Weight: 249.27
- MDL number: MFCD00004071
- EINECS: 201-637-9
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-12-18 14:07:02
What is 1-(2-Pyridylazo)-2-naphthol?
Chemical properties
orange crystals
The Uses of 1-(2-Pyridylazo)-2-naphthol
1-(2-Pyridylazo)-2-naphthol is an indicator of transition metals. 1-(2-Pyridylazo)-2-naphthol is an indicator in complexometry and a reagent for the extraction and spectrophotometric determination of many transition metals. Dyes and metabolites.
What are the applications of Application
1-(2-Pyridylazo)-2-naphthol is an indicator of transition metals
Definition
ChEBI: 1-(2-pyridin-2-yldiazenyl)-2-naphthol is a member of naphthols.
General Description
1-(2-Pyridylazo)-2-naphthol (PAN), an orange colored dye, is commonly used as an acid-base indicator. It can form chelates with metal ions, which makes it a valuable indicator in complexometric titrations. PAN is also a spectrophotometric reagent, which can extract metal chelates into an organic solvent.
Agricultural Uses
1-(2-Pyridylazo)-2-naphthol is a hard stratum of strongly compacted soil caused by continual plowing to the same depth of hardened soil which has high clay content. The precipitated iron and silicates cement the soil particles and form pans. 1-(2-Pyridylazo)-2-naphthol often impede drainage and root growth. It can be broken up using a subsoiler .
Purification Methods
Purify PAN by repeated crystallisation from EtOH or MeOH. It can also be purified by sublimation under vacuum. Purity can be checked by TLC using a mixed solvent (pet ether/Et2O/EtOH; 10:10:1) on a silica gel plate. It has pK1 1.9 and pK2 12.2 in 20% aqueous ethoxyethanol. It chelates with copper [Pease & Williams Anal Chem 31 1046 1959]. [Beilstein 22 I 694, 22 III/IV 7073, 22/4 V 618.]
Properties of 1-(2-Pyridylazo)-2-naphthol
Melting point: | 138-141 °C (lit.) |
Boiling point: | 392.37°C (rough estimate) |
Density | 1.1469 (rough estimate) |
refractive index | 1.5700 (estimate) |
storage temp. | Store at +5°C to +30°C. |
pka | 8.86±0.50(Predicted) |
form | Powder/Solid |
color | green to red, upon chelation with metal |
Water Solubility | Insoluble |
BRN | 206390 |
Stability: | Stable. Incompatible with strong oxidizing agents, strong bases. |
CAS DataBase Reference | 85-85-8(CAS DataBase Reference) |
NIST Chemistry Reference | 2-Naphthalenol, 1-(2-pyridinylazo)-(85-85-8) |
EPA Substance Registry System | 2-Naphthalenol, 1-(2-pyridinylazo)- (85-85-8) |
Safety information for 1-(2-Pyridylazo)-2-naphthol
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P280:Wear protective gloves/protective clothing/eye protection/face protection. P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P405:Store locked up. |
Computed Descriptors for 1-(2-Pyridylazo)-2-naphthol
1-(2-Pyridylazo)-2-naphthol manufacturer
GSP Dyes and Chemicals Pvt.Ltd
Anand Agencies
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