β-D-Glucose pentaacetate
Synonym(s):1,2,3,4,6-Penta-O-acetyl-β-D -glucopyranose;beta-D -Glucose pentaacetate
- CAS NO.:604-69-3
- Empirical Formula: C16H22O11
- Molecular Weight: 390.34
- MDL number: MFCD00006597
- EINECS: 210-074-8
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-11-19 23:02:33
What is β-D-Glucose pentaacetate?
Chemical properties
white to beige powder
The Uses of β-D-Glucose pentaacetate
β-D-Glucose Pentaacetate is used in biochemical reaction and also used as an active pharmaceutical intermediate. Further, it is used to stimulate insulin release in rat pancreatic islets.
The Uses of β-D-Glucose pentaacetate
beta-D-Glucose pentaacetate was reported to stimulate insulin release in rat pancreatic islets.
What are the applications of Application
β-D-Glucose Pentaacetate is an enantiomer of D-glucose pentaacetate
Definition
ChEBI: Beta-d-glucose pentaacetate is an organooxygen compound. It is functionally related to a hexacarboxylic acid.
Purification Methods
Crystallise the pentaacetate from MeOH or EtOH. It is best purified by recrystallising 160g from 1L of hot 95% EtOH (charcoal) and filtering hot. It is important that as soon as the temperature of the filtrate cools to ~20o it is filtered off. Note that some -D-isomer will crystallise out if a prolonged crystallisation period is allowed. Further crystallisation in this manner and drying in a vacuum over CaCl2 will give pure -D-anomer which has m 132o, [] D 20 + 4o (c 5, CHCl3). [Wolfrom & Thompson Methods in Carbohydrate Chemistry II 212 1963, Academic Press, Krahl & Cori Biochemical Preparations 1 33 1955, Beilstein 17/7 V 319.]
Properties of β-D-Glucose pentaacetate
Melting point: | 130-132 °C |
Boiling point: | 435.58°C (rough estimate) |
alpha | 5 º (c=1, CHCl3) |
Density | 1,274 g/cm3 |
refractive index | 4.5 ° (C=5, CHCl3) |
storage temp. | Inert atmosphere,Room Temperature |
solubility | chloroform: 0.1 g/mL, clear, colorless |
form | Crystalline Powder |
color | White to off-white |
Odor | at 100.00?%. odorless |
optical activity | [α]20/D +4.2°, c = 1 in chloroform |
Water Solubility | Soluble in chloroform and methanol. Insoluble in water. |
BRN | 98851 |
CAS DataBase Reference | 604-69-3(CAS DataBase Reference) |
NIST Chemistry Reference | Acetyl 2,3,4,6-tetra-o-acetyl-«beta»-D-glucopyranoside(604-69-3) |
Safety information for β-D-Glucose pentaacetate
Signal word | Danger |
Pictogram(s) |
Corrosion Corrosives GHS05 |
GHS Hazard Statements |
H314:Skin corrosion/irritation |
Precautionary Statement Codes |
P280:Wear protective gloves/protective clothing/eye protection/face protection. P310:Immediately call a POISON CENTER or doctor/physician. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for β-D-Glucose pentaacetate
InChIKey | LPTITAGPBXDDGR-XJGFBQBWSA-N |
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