VANADIUM(III) BROMIDE
- CAS NO.：13470-26-3
- Empirical Formula: Br3V
- Molecular Weight: 290.65
- MDL number: MFCD00049695
- EINECS: 236-736-6
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-10-17 17:11:57
What is VANADIUM(III) BROMIDE?
Chemical properties
-20 mesh; black powder(s); sensitive to moisture [STR93]
The Uses of VANADIUM(III) BROMIDE
Vanadium(III) bromide is used as a catalyst for C(sp3)-H fluorination reactions especially the benzylic fluorination.
Safety Profile
Poison by subcutaneous route. When heated to decomposition it emits toxic fumes of VOx and Br-. See also VANADIUM COMPOUNDS and BROMIDES.
Properties of VANADIUM(III) BROMIDE
| Density | 4 g/cm3 |
| solubility | reacts with H2O |
| form | Powder |
| Specific Gravity | 4.00?’ |
| color | black |
| Water Solubility | Soluble in water and tetrahydrofuran. |
| Sensitive | Moisture Sensitive |
| Exposure limits | NIOSH: Ceiling 0.05 mg/m3 |
| EPA Substance Registry System | Vanadium bromide (VBr3) (13470-26-3) |
Safety information for VANADIUM(III) BROMIDE
| Signal word | Danger |
| Pictogram(s) |
 Corrosion Corrosives GHS05 |
| GHS Hazard Statements |
H314:Skin corrosion/irritation H318:Serious eye damage/eye irritation |
| Precautionary Statement Codes |
P280:Wear protective gloves/protective clothing/eye protection/face protection. P310:Immediately call a POISON CENTER or doctor/physician. P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P405:Store locked up. |
Computed Descriptors for VANADIUM(III) BROMIDE
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