TUNGSTEN SELENIDE
Synonym(s):Monolayer tungsten selenide;Tungsten (IV) selenide;Tungsten selenide;WSe2 flakes
- CAS NO.:12067-46-8
- Empirical Formula: Se2W
- Molecular Weight: 341.78
- MDL number: MFCD00049703
- EINECS: 235-078-7
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-05-31 14:50:46
What is TUNGSTEN SELENIDE?
Chemical properties
-325 mesh black powder(s); dry, solid lubricant with exceptional stability at high temperatures, and in high vacuum; used in the form of 99.8% pure material as a sputtering target to produce lubricant films [HAW93] [CER91] [AES93]
The Uses of TUNGSTEN SELENIDE
Tungsten(IV) selenide is used as an important compound in electrochemical solar cells. It acts as a stable semiconductor.
The Uses of TUNGSTEN SELENIDE
The two dimensional layered inorganic nanomaterials have drawn significant attention recently owing to their thickness dependent physical and chemical properties. They find applications in photocatalysis, phtotovoltaics, gas sensing, lithium ion batteries, field effect transistors, spintronics etc. Transition metal dischalcogenides represent an important class of inorganic 2D materials having the aforementioned applications.
The Uses of TUNGSTEN SELENIDE
Owing to the thickness dependent physical and chemical properties, the two dimensional layered inorganic nanomaterials have drawn significant attention recently. They find applications in photocatalysis, phtotovoltaics, gas sensing, lithium ion batteries, field effect transistors, spintronics etc. Transition metal dichalcogenides represent an important class of inorganic 2D materials having aforementioned applications. The CVD grown monolayer films of MoS2, MoSe2, WS2 and WSe2 on insulating substrates such as SiO2 and sapphire are well suited for electronic and photovoltaic devices.
Definition
Lamellarstructured, dry, solid lubricant with exceptionally high temperature and high vacuum stability. Retains its lubricity to temperatures as low as ?265C.
Hazard
TLV: 5 mg(W)/m3.
Structure and conformation
Tungsten diselenide, WSe2, has a hexagonal crystalline structure comparable to MoS2. Every tungsten atom is covalently bonded to six selenium ligands in a trigonal prismatic coordination sphere, and each selenium is bonded to three
tungsten atoms in a pyramidal geometry. Heating thin films of tungsten under pressure from gaseous selenium and high
temperatures ( . 527℃/800K) using the sputter deposition technique leads to the films crystallizing in hexagonal structures with the correct stoichiometric ratio.
W+ 2Se→WSe2
Properties of TUNGSTEN SELENIDE
Density | 9.32 |
RTECS | YO7714000 |
form | Powder, 10μm |
color | gray hexagonal, hexane crystals, crystalline |
Water Solubility | Insoluble in water. |
Exposure limits | ACGIH: TWA 0.2 mg/m3; TWA 3 mg/m3 NIOSH: IDLH 1 mg/m3; TWA 5 mg/m3; TWA 0.2 mg/m3; STEL 10 mg/m3 |
CAS DataBase Reference | 12067-46-8(CAS DataBase Reference) |
EPA Substance Registry System | Tungsten selenide (WSe2) (12067-46-8) |
Safety information for TUNGSTEN SELENIDE
Signal word | Danger |
Pictogram(s) |
Skull and Crossbones Acute Toxicity GHS06 Health Hazard GHS08 Environment GHS09 |
GHS Hazard Statements |
H373:Specific target organ toxicity, repeated exposure H410:Hazardous to the aquatic environment, long-term hazard |
Precautionary Statement Codes |
P260:Do not breathe dust/fume/gas/mist/vapours/spray. P403+P233:Store in a well-ventilated place. Keep container tightly closed. |
Computed Descriptors for TUNGSTEN SELENIDE
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