Trimethyl thiazole
- CAS NO.:13623-11-5
- Empirical Formula: C6H9NS
- Molecular Weight: 127.21
- MDL number: MFCD00005332
- EINECS: 237-107-9
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-12-18 14:08:57
What is Trimethyl thiazole?
Chemical properties
clear colourless to yellow liquid
Chemical properties
2,4,5-Trimethyl thiazole has a cocoa, dark chocolate, nutty, coffee taste.
Occurrence
Reported found in kohlrabi, French fried potato, boiled and cooked potato, fried chicken, raw chicken, boiled and cooked beef, grilled and roasted beef, lamb and mutton liver, boiled and cooked cured pork, coffee, black tea, coriander seed, katsuobushi (dried bonito), cooked shrimp and other natural sources.
The Uses of Trimethyl thiazole
2,4,5-Trimethylthiazole was employed as internal standard in the gas chromatographic determination of aldehydes in alcoholic beverages.
Definition
ChEBI: A 1,3-thiazole that is thiazole in which all three hydrogens are replaced by methyl groups. A Maillard reaction product, it is a flavour component in many cooked foods, including cooked meats and potatoes.
Preparation
By decarboxylation of 2,4-dimethylthiazole-5-acetic acid; by reacting acetamide and phosphorous pentasulfide with methyl-α-bromoethyl ketone.
Aroma threshold values
Detection: 50 ppb
Taste threshold values
Taste characteristics at 10 ppm: nutty, cocoa and green vegetative-like with roasted earthy nuances.
General Description
2,4,5-Trimethylthiazole is a volatile oxidant and was isolated during microwave-induced L-cysteine/D-glucose Maillard model system.
Properties of Trimethyl thiazole
Melting point: | -32.4°C |
Boiling point: | 166-167 °C/717 mmHg (lit.) |
Density | 1.013 g/mL at 25 °C (lit.) |
refractive index | n |
FEMA | 3325 | 2,4,5-TRIMETHYLTHIAZOLE |
Flash point: | 133 °F |
storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
form | liquid |
pka | pK1:4.55 (25°C,μ=0.1) |
Specific Gravity | 1.311.013 |
color | Light orange to Yellow to Green |
Odor | at 1.00 % in dipropylene glycol. musty nutty vegetable cocoa hazelnut chocolate coffee |
JECFA Number | 1036 |
BRN | 107148 |
CAS DataBase Reference | 13623-11-5(CAS DataBase Reference) |
NIST Chemistry Reference | Thiazole, 2,4,5-trimethyl-(13623-11-5) |
EPA Substance Registry System | Thiazole, trimethyl- (13623-11-5) |
Safety information for Trimethyl thiazole
Signal word | Danger |
Pictogram(s) |
Flame Flammables GHS02 Corrosion Corrosives GHS05 Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H226:Flammable liquids H302:Acute toxicity,oral H315:Skin corrosion/irritation H318:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for Trimethyl thiazole
New Products
Tert-butyl bis(2-chloroethyl)carbamate 4-Methylphenylacetic acid N-Boc-D-alaninol N-BOC-D/L-ALANINOL N-octanoyl benzotriazole 3-Morpholino-1-(4-nitrophenyl)-5,6-dihydropyridin- 2(1H)-one Furan-2,5-Dicarboxylic Acid DIETHYL AMINOMALONATE HYDROCHLORIDE 1,1’-CARBONYLDIIMIDAZOLE R-2-BENZYLOXY PROPIONIC ACID 1,1’-CARBONYLDI (1,2-4 TRIAZOLE) N-METHYL INDAZOLE-3-CARBOXYLIC ACID (2-Hydroxyphenyl)acetonitrile 4-Bromopyrazole 5-BROMO-2CYANO PYRIDINE 5,6-Dimethoxyindanone 5-broMo-2-chloro-N-cyclopentylpyriMidin-4-aMine 2-(Cyanocyclohexyl)acetic acid 4-methoxy-3,5-dinitropyridine 1-(4-(aminomethyl)benzyl)urea hydrochloride 2-aminopropyl benzoate hydrochloride diethyl 2-(2-((tertbutoxycarbonyl)amino) ethyl)malonate tert-butyl 4- (ureidomethyl)benzylcarbamate Ethyl-2-chloro((4-methoxyphenyl)hydrazono)acetateRelated products of tetrahydrofuran
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