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HomeProduct name listTriethylamine trihydrofluoride

Triethylamine trihydrofluoride

Synonym(s):Hydrogen fluoride triethylamine;TREAT-HF;Triethylamine trishydrofluoride

  • CAS NO.:73602-61-6
  • Empirical Formula: C6H18F3N
  • Molecular Weight: 161.21
  • MDL number: MFCD00043294
  • EINECS: 277-550-5
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-09-11 18:44:42
Triethylamine trihydrofluoride Structural

What is Triethylamine trihydrofluoride?

Chemical properties

clear yellow liquid

The Uses of Triethylamine trihydrofluoride

Triethylamine trihydrofluoride acts as a mild and selective fluorinating agent used in the synthesis of acid fluorides and alkyl fluorides. It is also used in the synthesis of vicinal difluorides from epoxides, 3-fluoroazetidine. It is utilized as a selective reagent for the cleavage of O-silyl groups in carbohydrates, nucleotides and cyanohydrins. It is actively involved in the electrochemical fluorodeiodination of alkyl iodides and fluorodesilylation in beta-lactams.

The Uses of Triethylamine trihydrofluoride

Mild and selective reagent that has been used in the fluorination of a wide variety of compounds. For a review, see Aldrichimica Acta.

General Description

Triethylamine trihydrofluoride (TREAT-HF) is a mild and selective reagent for the fluorination of a wide variety of compounds.

Properties of Triethylamine trihydrofluoride

Melting point: -29--27°C
Boiling point: 70 °C15 mm Hg(lit.)
Density  0.989 g/mL at 25 °C(lit.)
refractive index  n20/D 1.3915(lit.)
Flash point: 190 °F
storage temp.  Store below +30°C.
solubility  soluble in Chloroform, Hexane
form  Liquid
Specific Gravity 0.989
color  Clear yellow to brown
PH 3 (H2O, 20℃)(saturated aqueous solution)
Water Solubility  soluble
Sensitive  Hygroscopic
BRN  5522945
Exposure limits ACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3
CAS DataBase Reference 73602-61-6(CAS DataBase Reference)
EPA Substance Registry System Ethanamine, N,N-diethyl-, trihydrofluoride (73602-61-6)

Safety information for Triethylamine trihydrofluoride

Signal word Danger
Pictogram(s)
ghs
Corrosion
Corrosives
GHS05
ghs
Skull and Crossbones
Acute Toxicity
GHS06
GHS Hazard Statements H314:Skin corrosion/irritation
Precautionary Statement Codes P260:Do not breathe dust/fume/gas/mist/vapours/spray.
P270:Do not eat, drink or smoke when using this product.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Triethylamine trihydrofluoride

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