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HomeProduct name listTriethyl 2-fluoro-2-phosphonoacetate

Triethyl 2-fluoro-2-phosphonoacetate

Synonym(s):2-Fluoro-2-phosphonoacetic acid triethyl ester;Diethyl [(ethoxycarbonyl)fluoromethyl]phosphonate;Ethyl diethylphosphonofluoroacetate

  • CAS NO.:2356-16-3
  • Empirical Formula: C8H16FO5P
  • Molecular Weight: 242.18
  • MDL number: MFCD00134400
  • EINECS: 627-648-2
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-04-23 13:52:06
Triethyl 2-fluoro-2-phosphonoacetate Structural

What is Triethyl 2-fluoro-2-phosphonoacetate?

Chemical properties

clear colorless liquid

The Uses of Triethyl 2-fluoro-2-phosphonoacetate

Reactant for:

  • Diels-Alder reactions
  • Biosynthesis of terpene
  • Stereoselective synthesis of unsaturated esters, fluorides and nitriles from the reactions of aldehydes and ketones using Wadsworth-Emmons phosphonates
  • Synthesis of quinolones
  • Horner-Wadsworth-Emmons asymmetric hydration
  • Addition reactions and the subsequent application to click chemistry
  • Asymmetric intermolecular Stetter reactions

Synthesis Reference(s)

The Journal of Organic Chemistry, 60, p. 4730, 1995 DOI: 10.1021/jo00120a014

Properties of Triethyl 2-fluoro-2-phosphonoacetate

Boiling point: 75 °C0.01 mm Hg(lit.)
Density  1.194 g/mL at 25 °C(lit.)
refractive index  n20/D 1.425(lit.)
Flash point: 165 °F
storage temp.  Keep in dark place,Inert atmosphere,Room temperature
form  clear liquid
color  Colorless to Almost colorless
Specific Gravity 1.194
BRN  1912161
CAS DataBase Reference 2356-16-3(CAS DataBase Reference)

Safety information for Triethyl 2-fluoro-2-phosphonoacetate

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H227:Flammable liquids
H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405:Store locked up.

Computed Descriptors for Triethyl 2-fluoro-2-phosphonoacetate

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