trans-2-Hexen-1-ol

Synonym(s):(E)-2-Hexen-1-ol;(E)-hex-2-en-1-ol

CAS NO.：928-95-0
Empirical Formula: C6H12O
Molecular Weight: 100.16
MDL number: MFCD00002927
EINECS: 213-191-2
SAFETY DATA SHEET (SDS)
Update Date: 2024-11-05 19:05:58

What is trans-2-Hexen-1-ol?

Chemical properties

colourless liquid

Chemical properties

(E)-2-Hexen-1-ol occurs in many fruits and has a fruity, green odor, which is sweeter than that of the isomeric (Z)-3- hexen-1-ol and is, therefore, preferred in aroma compositions.

The Uses of trans-2-Hexen-1-ol

trans-2-Hexen-1-ol was used to evaluate the quality of protected designation of virgin olive oils by headspace solid-phase microextraction-gas chromatography using flame ionization detection and multivariate analysis. It was also used in encapsulation of vanadium catalysts in inorganic and hybrid matrices using sol-gel method.

What are the applications of Application

trans-2-Hexen-1-ol is A useful chemical to study olive oils and industrial practices of vanadium catalysts

Definition

ChEBI: 2-hexen-1-ol is a primary allylic alcohol that is 2-hexene in which a hydrogen at position 1 has been replaced by a hydroxy group. It has a role as a plant metabolite. It is an alkenyl alcohol and a primary allylic alcohol.

Synthesis Reference(s)

Journal of the American Chemical Society, 93, p. 2792, 1971 DOI: 10.1021/ja00740a040
Tetrahedron Letters, 24, p. 3413, 1983 DOI: 10.1016/S0040-4039(00)86286-3

General Description

trans-2-Hexen-1-ol undergoes allylic epoxidation to yield (2R,3R)-(+)-3-propyloxiranemethanol in high pressure carbon dioxide.

Biochem/physiol Actions

Taste at 2.0-9.0 ppm

Properties of trans-2-Hexen-1-ol

Melting point:	54.63°C
Boiling point:	158-160 °C(lit.)
Density	0.849 g/mL at 25 °C(lit.)
vapor pressure	1hPa at 20℃
FEMA	2562 \| 2-HEXEN-1-OL
refractive index	n20/D 1.438(lit.)
Flash point:	130 °F
storage temp.	2-8°C
form	Liquid
pka	14.45±0.10(Predicted)
color	Clear colorless
Odor	at 10.00 % in dipropylene glycol. fresh green leafy fruity unripe banana
Water Solubility	Slightly soluble in water
BRN	1719709
Stability:	Stable. Flammable. Incompatible with strong oxidizing agents, strong acids.
CAS DataBase Reference	928-95-0(CAS DataBase Reference)
NIST Chemistry Reference	2-Hexen-1-ol, (E)-(928-95-0)
EPA Substance Registry System	(E)-2-Hexen-1-ol (928-95-0)

Safety information for trans-2-Hexen-1-ol

Signal word	Warning
Pictogram(s)	Flame Flammables GHS02
GHS Hazard Statements	H226:Flammable liquids
Precautionary Statement Codes	P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P370+P378:In case of fire: Use … for extinction.