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HomeProduct name listTitanium tetraisopropanolate

Titanium tetraisopropanolate

Synonym(s):Tetraisopropyl orthotitanate;TTIP

  • CAS NO.:546-68-9
  • Empirical Formula: C12H28O4Ti
  • Molecular Weight: 284.22
  • MDL number: MFCD00008871
  • EINECS: 208-909-6
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-10-24 21:11:45
Titanium tetraisopropanolate Structural

What is Titanium tetraisopropanolate?

Chemical properties

colourless to light yellow liquid

The Uses of Titanium tetraisopropanolate

Catalyst especially for asymmetric induction in organic syntheses; in preparation of nanosized TiO2. Complexing agent in sol-gel process.

The Uses of Titanium tetraisopropanolate

Titanium tetraisopropanolate
To a solution of 10% AcOH in MeOH was added the SM (1 equiv) and dry acetone (5 equiv). The solution was stirred at RT 1 h, after which time it was cooled to 0 C and treated with NaCNBH3 (1.5 equiv). The reaction was stirred at RT for 5 h. The mixture was concentrated and the residue brought to pH = 10 using Na2CO3. The mixture was extracted with EtOAc and the org layer was washed with H2O, brine, dried (Na2SO4), and concentrated to dryness. The crude material was purified by silica gel column chromatography (2% MeOH/DCM) to provide the pdt as a yellow solid.

The Uses of Titanium tetraisopropanolate

Titanium(IV) isopropoxide is used as a precursor for the preparation of titanium and barium-strontium-titanate thin films. It is useful to make porous titanosilicates and potential ion-exchange materials for cleanup of radioactive wastes. It is an active component of Sharpless epoxidation as well as involved in the synthesis of chiral epoxides. In Kulinkovich reaction, it is involved as a catalyst in the preparation of cyclopropanes.

What are the applications of Application

Titanium(IV) isopropoxide is a precursor for the preparation of Titania

Definition

ChEBI: Titanium(IV) isopropoxide is a titanium coordination entity consisting of a titanium(IV) cation with four propan-2-olate anions as counterions.

General Description

Tetraisopropyl titanate appears as a water-white to pale-yellow liquid with an odor like isopropyl alcohol. About the same density as water. Vapors heavier than air.

Air & Water Reactions

Highly flammable. Fumes in air. Soluble in water. Decomposes rapidly in water to form flammable isopropyl alcohol.

Reactivity Profile

Metal alkyls, such as TETRAISOPROPYL TITANATE, are reducing agents and react rapidly and dangerously with oxygen and with other oxidizing agents, even weak ones. Thus, they are likely to ignite on contact with alcohols.

Health Hazard

Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Flammability and Explosibility

Flammable

Purification Methods

Dissolve it in dry *C6H6 , filter if a solid separates, evaporate and fractionate. It is hydrolysed by H2O to give solid Ti2O(iso-OPr)2 m ca 48o. [Bradley et al. J Chem Soc 2027, 1952, Bradley et al. J Chem Soc 469 1957, Beilstein 1 II 328, 1 IV 1469S.]

Properties of Titanium tetraisopropanolate

Melting point: 14-17 °C(lit.)
Boiling point: 232 °C(lit.)
Density  0.96 g/mL at 20 °C(lit.)
vapor pressure  60.2hPa at 25℃
refractive index  n20/D 1.464(lit.)
Flash point: 72 °F
storage temp.  Flammables area
solubility  Soluble in anhydrous ethanol, ether, benzene and chloroform.
form  Liquid
appearance Colorless liquid
color  Colorless to pale yellow
Specific Gravity 0.955
Water Solubility  HYDROLYSIS
FreezingPoint  14.8℃
Sensitive  Moisture Sensitive
Hydrolytic Sensitivity 7: reacts slowly with moisture/water
Merck  14,9480
BRN  3679474
Stability: Stable, but decomposes in the presence of moisture. Incompatible with aqueous solutions, strong acids, strong oxidizing agents. Flammable.
CAS DataBase Reference 546-68-9(CAS DataBase Reference)
EPA Substance Registry System 2-Propanol, titanium(4+) salt (546-68-9)

Safety information for Titanium tetraisopropanolate

Signal word Warning
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H226:Flammable liquids
H319:Serious eye damage/eye irritation
H336:Specific target organ toxicity,single exposure; Narcotic effects
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233:Keep container tightly closed.
P240:Ground/bond container and receiving equipment.
P241:Use explosion-proof electrical/ventilating/lighting/…/equipment.
P242:Use only non-sparking tools.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Titanium tetraisopropanolate

InChIKey VXUYXOFXAQZZMF-UHFFFAOYSA-N

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