Titanium tetraisopropanolate

Synonym(s):Tetraisopropyl orthotitanate;TTIP

CAS NO.：546-68-9
Empirical Formula: C12H28O4Ti
Molecular Weight: 284.22
MDL number: MFCD00008871
EINECS: 208-909-6
SAFETY DATA SHEET (SDS)
Update Date: 2023-12-22 17:53:22

Titanium tetraisopropanolate Structural Picture

What is Titanium tetraisopropanolate?

The Uses of Titanium tetraisopropanolate

Catalyst especially for asymmetric induction in organic syntheses; in preparation of nanosized TiO2. Complexing agent in sol-gel process.

The Uses of Titanium tetraisopropanolate

Titanium tetraisopropanolate
To a solution of 10% AcOH in MeOH was added the SM (1 equiv) and dry acetone (5 equiv). The solution was stirred at RT 1 h, after which time it was cooled to 0 C and treated with NaCNBH3 (1.5 equiv). The reaction was stirred at RT for 5 h. The mixture was concentrated and the residue brought to pH = 10 using Na2CO3. The mixture was extracted with EtOAc and the org layer was washed with H2O, brine, dried (Na2SO4), and concentrated to dryness. The crude material was purified by silica gel column chromatography (2% MeOH/DCM) to provide the pdt as a yellow solid.

What are the applications of Application

Titanium(IV) isopropoxide is a precursor for the preparation of Titania

Properties of Titanium tetraisopropanolate

Melting point:	14-17 °C(lit.)
Boiling point:	232 °C(lit.)
Density	0.96 g/mL at 20 °C(lit.)
Flash point:	72 °F
storage temp.	Flammables area
solubility	Soluble in anhydrous ethanol, ether, benzene and chloroform.
form	Liquid
appearance	Colorless liquid
color	Colorless to pale yellow
Water Solubility	HYDROLYSIS
FreezingPoint	14.8℃
Sensitive	Moisture Sensitive

Safety information for Titanium tetraisopropanolate

Signal word	Warning
Pictogram(s)	Flame Flammables GHS02 Exclamation Mark Irritant GHS07
GHS Hazard Statements	H226:Flammable liquids H319:Serious eye damage/eye irritation H336:Specific target organ toxicity,single exposure; Narcotic effects
Precautionary Statement Codes	P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P233:Keep container tightly closed. P240:Ground/bond container and receiving equipment. P241:Use explosion-proof electrical/ventilating/lighting/…/equipment. P242:Use only non-sparking tools. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.