Titanium ethoxide
Synonym(s):Tetraethyl orthotitanate;Tetraethyl titanate
- CAS NO.:3087-36-3
- Empirical Formula: C8H20O4Ti
- Molecular Weight: 228.11
- MDL number: MFCD00009071
- EINECS: 221-410-8
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-11-20 17:10:30
What is Titanium ethoxide?
Chemical properties
colourless liquid
The Uses of Titanium ethoxide
Titanium ethoxide is used widely as a precursor for the synthesis of Ti4+ ions titania nanoparticles by various techniques such as :
- in the sol-gel synthesis of free-standing ferroelectric lead zirconate titanate nanoparticles
- spherical titania cores, produced either by hydrolysis of Ti(IV) ethoxide droplets in contact with water vapor or
- by preadsorption of the titanium alkoxides into/onto the clay mineral platelets and their subsequent hydrolysis and calcination.
The Uses of Titanium ethoxide
Titanium(IV) ethoxide is used in organic synthesis and material science. It is involved in the synthesis of anti-perspirants and antifungal agents. Furthermore, it is used to prepare carbon films in association with silicon dioxide. It is also used as a precursor for the synthesis of Ti4+ ions titanium nanoparticles by various methods.
The Uses of Titanium ethoxide
Titanium(IV) ethoxide can be used:
- As an activator and dehydrating agent for by condensation of (S)-(+)-p-toluenesulfinamide with aldehydes and ketones to form sulfinimines.
- As a Ti4+ ion source to form complexes of titanium (IV) acrylate with methacrylic acid.
- As a catalyst to synthesize esters of sterically hindered alcohols via transesterification reactions.
What are the applications of Application
Titanium(IV) ethoxide is a useful chemical used to produce anti-perisperants and antifungals and carbon films
What are the applications of Application
Titanium(IV) ethoxide can be used:
As an activator and dehydrating agent for by condensation of (S)-(+)-p-toluenesulfinamide with aldehydes and ketones to form sulfinimines.
As a Ti4+ ion source to form complexes of titanium (IV) acrylate with methacrylic acid.
As a catalyst to synthesize esters of sterically hindered alcohols via transesterification reactions.
Flammability and Explosibility
Flammable
Materials Uses
Titanium ethoxide is used widely as a precursor for the synthesis of Ti4+ ions titania nanoparticles by various techniques such as :
in the sol-gel synthesis of free-standing ferroelectric lead zirconate titanate nanoparticles
spherical titania cores, produced either by hydrolysis of Ti(IV) ethoxide droplets in contact with water vapor or
by preadsorption of the titanium alkoxides into/onto the clay mineral platelets and their subsequent hydrolysis and calcination.
Properties of Titanium ethoxide
Melting point: | 54°C |
Boiling point: | 150-152 °C10 mm Hg(lit.) |
Density | 1.088 g/mL at 25 °C(lit.) |
vapor pressure | 57.26hPa at 19.6℃ |
refractive index | n |
Flash point: | 84 °F |
storage temp. | 2-8°C |
solubility | Soluble in organic solvents. |
form | Liquid |
Specific Gravity | 1.107 (20℃) |
color | Pale yellow |
Water Solubility | reacts |
Sensitive | Moisture Sensitive |
BRN | 3678992 |
Exposure limits | ACGIH: TWA 200 ppm; STEL 400 ppm OSHA: TWA 400 ppm(980 mg/m3) NIOSH: IDLH 2000 ppm; TWA 400 ppm(980 mg/m3); STEL 500 ppm(1225 mg/m3) |
Stability: | Stability Incompatible with strong oxidizing agents, strong acids. May decompose upon exposure to air or moisture. |
CAS DataBase Reference | 3087-36-3(CAS DataBase Reference) |
NIST Chemistry Reference | Ti(OEt)4(3087-36-3) |
EPA Substance Registry System | Ethanol, titanium(4+) salt (3087-36-3) |
Safety information for Titanium ethoxide
Signal word | Warning |
Pictogram(s) |
Flame Flammables GHS02 Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H226:Flammable liquids H319:Serious eye damage/eye irritation |
Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for Titanium ethoxide
InChIKey | JMXKSZRRTHPKDL-UHFFFAOYSA-N |
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