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HomeProduct name listTitanium ethoxide

Titanium ethoxide

Synonym(s):Tetraethyl orthotitanate;Tetraethyl titanate

  • CAS NO.:3087-36-3
  • Empirical Formula: C8H20O4Ti
  • Molecular Weight: 228.11
  • MDL number: MFCD00009071
  • EINECS: 221-410-8
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-11-20 17:10:30
Titanium ethoxide Structural

What is Titanium ethoxide?

Chemical properties

colourless liquid

The Uses of Titanium ethoxide

Titanium ethoxide is used widely as a precursor for the synthesis of Ti4+ ions titania nanoparticles by various techniques such as :

  • in the sol-gel synthesis of free-standing ferroelectric lead zirconate titanate nanoparticles
  • spherical titania cores, produced either by hydrolysis of Ti(IV) ethoxide droplets in contact with water vapor or
  • by preadsorption of the titanium alkoxides into/onto the clay mineral platelets and their subsequent hydrolysis and calcination.

The Uses of Titanium ethoxide

Titanium(IV) ethoxide is used in organic synthesis and material science. It is involved in the synthesis of anti-perspirants and antifungal agents. Furthermore, it is used to prepare carbon films in association with silicon dioxide. It is also used as a precursor for the synthesis of Ti4+ ions titanium nanoparticles by various methods.

The Uses of Titanium ethoxide

Titanium(IV) ethoxide can be used:

  • As an activator and dehydrating agent for by condensation of (S)-(+)-p-toluenesulfinamide with aldehydes and ketones to form sulfinimines.
  • As a Ti4+ ion source to form complexes of titanium (IV) acrylate with methacrylic acid.
  • As a catalyst to synthesize esters of sterically hindered alcohols via transesterification reactions.

What are the applications of Application

Titanium(IV) ethoxide is a useful chemical used to produce anti-perisperants and antifungals and carbon films

What are the applications of Application

Titanium(IV) ethoxide can be used:
As an activator and dehydrating agent for by condensation of (S)-(+)-p-toluenesulfinamide with aldehydes and ketones to form sulfinimines.
As a Ti4+ ion source to form complexes of titanium (IV) acrylate with methacrylic acid.
As a catalyst to synthesize esters of sterically hindered alcohols via transesterification reactions.

Flammability and Explosibility

Flammable

Materials Uses

Titanium ethoxide is used widely as a precursor for the synthesis of Ti4+ ions titania nanoparticles by various techniques such as :
in the sol-gel synthesis of free-standing ferroelectric lead zirconate titanate nanoparticles
spherical titania cores, produced either by hydrolysis of Ti(IV) ethoxide droplets in contact with water vapor or
by preadsorption of the titanium alkoxides into/onto the clay mineral platelets and their subsequent hydrolysis and calcination.

Properties of Titanium ethoxide

Melting point: 54°C
Boiling point: 150-152 °C10 mm Hg(lit.)
Density  1.088 g/mL at 25 °C(lit.)
vapor pressure  57.26hPa at 19.6℃
refractive index  n20/D 1.505(lit.)
Flash point: 84 °F
storage temp.  2-8°C
solubility  Soluble in organic solvents.
form  Liquid
Specific Gravity 1.107 (20℃)
color  Pale yellow
Water Solubility  reacts
Sensitive  Moisture Sensitive
BRN  3678992
Exposure limits ACGIH: TWA 200 ppm; STEL 400 ppm
OSHA: TWA 400 ppm(980 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 400 ppm(980 mg/m3); STEL 500 ppm(1225 mg/m3)
Stability: Stability Incompatible with strong oxidizing agents, strong acids. May decompose upon exposure to air or moisture.
CAS DataBase Reference 3087-36-3(CAS DataBase Reference)
NIST Chemistry Reference Ti(OEt)4(3087-36-3)
EPA Substance Registry System Ethanol, titanium(4+) salt (3087-36-3)

Safety information for Titanium ethoxide

Signal word Warning
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H226:Flammable liquids
H319:Serious eye damage/eye irritation
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Titanium ethoxide

InChIKey JMXKSZRRTHPKDL-UHFFFAOYSA-N

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