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HomeProduct name listEthylene carbonate

Ethylene carbonate

Synonym(s):1,3-Dioxolan-2-one;1,3-Dioxolane-2-one;EC;Ethylene carbonate;Glycol carbonate

  • CAS NO.:96-49-1
  • Empirical Formula: C3H4O3
  • Molecular Weight: 88.06
  • MDL number: MFCD00005382
  • EINECS: 202-510-0
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-08-21 22:41:43
Ethylene carbonate Structural

What is Ethylene carbonate?

Chemical properties

colourless crystals

The Uses of Ethylene carbonate

Solvent for many polymers and resins, plasticisers, rubbers and textiles.Ethylene carbonate is used as a polar solvent and a high permittivity component of electrolytes in lithium batteries. It finds application in surface coatings, dyes, fibers and plastics. It is also used as a plasticizer and as a precursor to vinylene carbonate. Further, it is used in the preparation of dimethyl carbonate, which acts as a useful solvent and a mild methylating agent.

The Uses of Ethylene carbonate

Ethylene carbonate has been used:
In the synthesis of aliphatic polyurethanes using diamines and diols.
As a precursor for ring-opening polymerization using KOH as initiator.
As a reactant in the preparation of dimethyl carbonate, glycerol carbonate by transesterification reaction.

The Uses of Ethylene carbonate

Ethylene carbonate is an ester of ethylene glycol and carbonic acid. Ethylene carbonate is used as a polar solvent with a molecular dipole moment of 4.9 D, only 0.1 D lower than that of propylene carb onate. It can be used as a high permittivity component of electrolytes in lithium batteries.

Definition

ChEBI: Ethylene carbonate is a carbonate ester.

Flammability and Explosibility

Non flammable

Purification Methods

Dry 1,3-dioxolan-2-one over P2O5, then fractionally distil it at low or atmospheric pressure. Recrystallise it from dry Et2O (plates, m 36.5o, 38.5-40o was also reported). It is soluble in H2O. [Beilstein 19 II 135,19 III/IV 1556, 19/4 V 6.]

Properties of Ethylene carbonate

Melting point: 35-38 °C(lit.)
Boiling point: 243-244 °C740 mm Hg(lit.)
Density  1.321 g/mL at 25 °C(lit.)
vapor density  3.04 (vs air)
vapor pressure  0.02 mm Hg ( 36.4 °C)
refractive index  1.4199
Flash point: 320 °F
storage temp.  Store below +30°C.
solubility  H2O: 1 M at 20 °C, clear, colorless
form  Crystalline Low Melting Solid
pka 3.86[at 20 ℃]
Specific Gravity 1.321
color  White to yellow
PH 7 (200g/l, H2O, 20℃)
Odor odorless
explosive limit 3.6-16.1%(V)
Water Solubility  214 g/L (20 ºC)
BRN  106249
Dielectric constant 69.4(91℃)
Stability: Stable. Incompatible with strong oxidizing agents, acids, bases, reducing agents.
CAS DataBase Reference 96-49-1(CAS DataBase Reference)
NIST Chemistry Reference Ethylene carbonate(96-49-1)
EPA Substance Registry System Ethylene carbonate (96-49-1)

Safety information for Ethylene carbonate

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
ghs
Health Hazard
GHS08
GHS Hazard Statements H302:Acute toxicity,oral
H319:Serious eye damage/eye irritation
H373:Specific target organ toxicity, repeated exposure
Precautionary Statement Codes P260:Do not breathe dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P270:Do not eat, drink or smoke when using this product.
P314:Get medical advice/attention if you feel unwell.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Ethylene carbonate

InChIKey KMTRUDSVKNLOMY-UHFFFAOYSA-N

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