Ethylene carbonate
Synonym(s):1,3-Dioxolan-2-one;1,3-Dioxolane-2-one;EC;Ethylene carbonate;Glycol carbonate
- CAS NO.:96-49-1
- Empirical Formula: C3H4O3
- Molecular Weight: 88.06
- MDL number: MFCD00005382
- EINECS: 202-510-0
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-12-18 14:08:52
What is Ethylene carbonate?
Chemical properties
colourless crystals
The Uses of Ethylene carbonate
Ethylene carbonate is an ester of ethylene glycol and carbonic acid. Ethylene carbonate is used as a polar solvent with a molecular dipole moment of 4.9 D, only 0.1 D lower than that of propylene carb onate. It can be used as a high permittivity component of electrolytes in lithium batteries.
The Uses of Ethylene carbonate
Solvent for many polymers and resins, plasticisers, rubbers and textiles.Ethylene carbonate is used as a polar solvent and a high permittivity component of electrolytes in lithium batteries. It finds application in surface coatings, dyes, fibers and plastics. It is also used as a plasticizer and as a precursor to vinylene carbonate. Further, it is used in the preparation of dimethyl carbonate, which acts as a useful solvent and a mild methylating agent.
The Uses of Ethylene carbonate
Ethylene carbonate has been used:
In the synthesis of aliphatic polyurethanes using diamines and diols.
As a precursor for ring-opening polymerization using KOH as initiator.
As a reactant in the preparation of dimethyl carbonate, glycerol carbonate by transesterification reaction.
Definition
ChEBI: Ethylene carbonate is a carbonate ester.
Flammability and Explosibility
Non flammable
Purification Methods
Dry 1,3-dioxolan-2-one over P2O5, then fractionally distil it at low or atmospheric pressure. Recrystallise it from dry Et2O (plates, m 36.5o, 38.5-40o was also reported). It is soluble in H2O. [Beilstein 19 II 135,19 III/IV 1556, 19/4 V 6.]
Properties of Ethylene carbonate
Melting point: | 35-38 °C(lit.) |
Boiling point: | 243-244 °C740 mm Hg(lit.) |
Density | 1.321 g/mL at 25 °C(lit.) |
vapor density | 3.04 (vs air) |
vapor pressure | 0.02 mm Hg ( 36.4 °C) |
refractive index | 1.4199 |
Flash point: | 320 °F |
storage temp. | Store below +30°C. |
solubility | H2O: 1 M at 20 °C, clear, colorless |
form | Crystalline Low Melting Solid |
pka | 3.86[at 20 ℃] |
Specific Gravity | 1.321 |
color | White to yellow |
PH | 7 (200g/l, H2O, 20℃) |
Odor | odorless |
explosive limit | 3.6-16.1%(V) |
Water Solubility | 214 g/L (20 ºC) |
BRN | 106249 |
Dielectric constant | 69.4(91℃) |
Stability: | Stable. Incompatible with strong oxidizing agents, acids, bases, reducing agents. |
CAS DataBase Reference | 96-49-1(CAS DataBase Reference) |
NIST Chemistry Reference | Ethylene carbonate(96-49-1) |
EPA Substance Registry System | Ethylene carbonate (96-49-1) |
Safety information for Ethylene carbonate
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 Health Hazard GHS08 |
GHS Hazard Statements |
H302:Acute toxicity,oral H319:Serious eye damage/eye irritation H373:Specific target organ toxicity, repeated exposure |
Precautionary Statement Codes |
P260:Do not breathe dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P270:Do not eat, drink or smoke when using this product. P314:Get medical advice/attention if you feel unwell. P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for Ethylene carbonate
InChIKey | KMTRUDSVKNLOMY-UHFFFAOYSA-N |
Ethylene carbonate manufacturer
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