Ethylene carbonate
Synonym(s):1,3-Dioxolan-2-one;1,3-Dioxolane-2-one;EC;Ethylene carbonate;Glycol carbonate
- CAS NO.:96-49-1
- Empirical Formula: C3H4O3
- Molecular Weight: 88.06
- MDL number: MFCD00005382
- EINECS: 202-510-0
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-08-21 22:41:43
What is Ethylene carbonate?
Chemical properties
colourless crystals
The Uses of Ethylene carbonate
Solvent for many polymers and resins, plasticisers, rubbers and textiles.Ethylene carbonate is used as a polar solvent and a high permittivity component of electrolytes in lithium batteries. It finds application in surface coatings, dyes, fibers and plastics. It is also used as a plasticizer and as a precursor to vinylene carbonate. Further, it is used in the preparation of dimethyl carbonate, which acts as a useful solvent and a mild methylating agent.
The Uses of Ethylene carbonate
Ethylene carbonate has been used:
In the synthesis of aliphatic polyurethanes using diamines and diols.
As a precursor for ring-opening polymerization using KOH as initiator.
As a reactant in the preparation of dimethyl carbonate, glycerol carbonate by transesterification reaction.
The Uses of Ethylene carbonate
Ethylene carbonate is an ester of ethylene glycol and carbonic acid. Ethylene carbonate is used as a polar solvent with a molecular dipole moment of 4.9 D, only 0.1 D lower than that of propylene carb onate. It can be used as a high permittivity component of electrolytes in lithium batteries.
Definition
ChEBI: Ethylene carbonate is a carbonate ester.
Flammability and Explosibility
Non flammable
Purification Methods
Dry 1,3-dioxolan-2-one over P2O5, then fractionally distil it at low or atmospheric pressure. Recrystallise it from dry Et2O (plates, m 36.5o, 38.5-40o was also reported). It is soluble in H2O. [Beilstein 19 II 135,19 III/IV 1556, 19/4 V 6.]
Properties of Ethylene carbonate
Melting point: | 35-38 °C(lit.) |
Boiling point: | 243-244 °C740 mm Hg(lit.) |
Density | 1.321 g/mL at 25 °C(lit.) |
vapor density | 3.04 (vs air) |
vapor pressure | 0.02 mm Hg ( 36.4 °C) |
refractive index | 1.4199 |
Flash point: | 320 °F |
storage temp. | Store below +30°C. |
solubility | H2O: 1 M at 20 °C, clear, colorless |
form | Crystalline Low Melting Solid |
pka | 3.86[at 20 ℃] |
Specific Gravity | 1.321 |
color | White to yellow |
PH | 7 (200g/l, H2O, 20℃) |
Odor | odorless |
explosive limit | 3.6-16.1%(V) |
Water Solubility | 214 g/L (20 ºC) |
BRN | 106249 |
Dielectric constant | 69.4(91℃) |
Stability: | Stable. Incompatible with strong oxidizing agents, acids, bases, reducing agents. |
CAS DataBase Reference | 96-49-1(CAS DataBase Reference) |
NIST Chemistry Reference | Ethylene carbonate(96-49-1) |
EPA Substance Registry System | Ethylene carbonate (96-49-1) |
Safety information for Ethylene carbonate
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 Health Hazard GHS08 |
GHS Hazard Statements |
H302:Acute toxicity,oral H319:Serious eye damage/eye irritation H373:Specific target organ toxicity, repeated exposure |
Precautionary Statement Codes |
P260:Do not breathe dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P270:Do not eat, drink or smoke when using this product. P314:Get medical advice/attention if you feel unwell. P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for Ethylene carbonate
InChIKey | KMTRUDSVKNLOMY-UHFFFAOYSA-N |
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