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HomeProduct name listSodium persulfate

Sodium persulfate

Synonym(s):Sodium peroxidisulfate;Sodium peroxodisulfate;Sodium persulfate, Peroxydisulfuric acid disodium salt

  • CAS NO.:7775-27-1
  • Empirical Formula: Na2O8S2
  • Molecular Weight: 238.1
  • MDL number: MFCD00003501
  • EINECS: 231-892-1
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-10-30 18:52:02
Sodium persulfate Structural

What is Sodium persulfate?

Chemical properties

White, crystalline powder. Soluble in water; decomposed by alcohol; decomposes in moist air.

The Uses of Sodium persulfate

Bleaching and oxidizing agent; promoter for emulsion polymerization reactions.

The Uses of Sodium persulfate

Sodium peroxydisulfate is used as a radical initiator for emulsion polymerization reactions like acrylonitrile butadiene styrene, detergent component, soil conditioner and soil remediation. It is also used for curing of formaldehyde adhesives. It acts as a bleaching agent and in the production of dyestuffs. It finds application in zinc and printed circuit boards and considered to be a replacement for ammonium persulfate in etching mixtures. Further, it is used in the preparation of diapocynin from apocynin. It plays a role in the conversion of phenols to para-diphenols in alkaline solution and of arylamines to aminophenols. It is actively involved in the Elbs persulfate oxidation and the Boyland-Sims oxidation reactions as an oxidizing agent.

The Uses of Sodium persulfate

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What are the applications of Application

Sodium persulfate is a strongly oxidizing chemical used as a bleaching and oxidizing agent

General Description

A white crystalline solid. Very irritating to skin and eyes. May be toxic by skin absorption. Used as a bleaching agent.

Air & Water Reactions

Water soluble. Decomposes slowly in moist air.

Reactivity Profile

Sodium persulfate is a strong oxidizing agent. Reacts with many combustible materials and reducing agents, often vigorously enough to start fires or cause explosions [Handling Chemicals Safely 1980 p. 855]. Decomposes gradually under ordinary conditions decomposition is promoted by moisture and heat [Merck]. Decomposed by alcohol and silver ions [Merck].

Hazard

By ingestion, strong irritant to tissue.

Health Hazard

Inhalation, ingestion or contact (skin, eyes) with vapors or substance may cause severe injury, burns or death. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may cause pollution.

Fire Hazard

These substances will accelerate burning when involved in a fire. Some may decompose explosively when heated or involved in a fire. May explode from heat or contamination. Some will react explosively with hydrocarbons (fuels). May ignite combustibles (wood, paper, oil, clothing, etc.). Containers may explode when heated. Runoff may create fire or explosion hazard.

Flammability and Explosibility

Non flammable

Safety Profile

Poison by intraperitoneal and intravenous routes. A powerful oxidizer; can cause fires. When heated to decomposition it emits toxic fumes of SOx and Na2O. See also SULFATES.

Properties of Sodium persulfate

Melting point: 100 °C
Density  2,4 g/cm3
vapor pressure  0Pa at 25℃
storage temp.  Store at +15°C to +25°C.
solubility  H2O: 1 M at 20 °C, clear, colorless
form  Solid
color  White to yellow
Specific Gravity 2.4
PH Range 2.5 - 4.0
PH 3.5-3.8 (100g/l, H2O, 20℃)
Odor Odorless
Water Solubility  550 g/L (20 ºC)
Merck  14,8656
Exposure limits ACGIH: TWA 0.1 mg/m3
Stability: Stability Unstable. Strong oxidizer. Contact with combustible material may cause fire. Incompatible with combustible material, strong reducing agents, strong bases, alcohols, aluminium, magnesium. Protect from moisture.
CAS DataBase Reference 7775-27-1(CAS DataBase Reference)
EPA Substance Registry System Sodium persulfate (7775-27-1)

Safety information for Sodium persulfate

Signal word Danger
Pictogram(s)
ghs
Flame Over Circle
Oxidizers
GHS03
ghs
Exclamation Mark
Irritant
GHS07
ghs
Health Hazard
GHS08
GHS Hazard Statements H272:Oxidising liquids;Oxidising solids
H302:Acute toxicity,oral
H315:Skin corrosion/irritation
H317:Sensitisation, Skin
H334:Sensitisation, respiratory
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P220:Keep/Store away from clothing/…/combustible materials.
P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352:IF ON SKIN: wash with plenty of soap and water.

Computed Descriptors for Sodium persulfate

InChIKey CHQMHPLRPQMAMX-UHFFFAOYSA-L

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