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HomeProduct name list(S)-Oxiranemethanol

(S)-Oxiranemethanol

Synonym(s):(S)-(−)-2,3-Epoxy-1-propanol;(S)-(−)-Oxirane-2-methanol

(S)-Oxiranemethanol Structural

What is (S)-Oxiranemethanol?

Chemical properties

Colorless to light yellow liqui

The Uses of (S)-Oxiranemethanol

Employed in the synthesis of chiral (E)-allylic alcohol side-chains for introduction into prostacyclin and prostaglandin frameworks by cross-metathesis.

What are the applications of Application

(S)-(?)-Glycidol is a chemical employed in the synthesis of chiral (E)-allylic alcohol side-chains

Definition

ChEBI: (S)-glycidol is a glycidol. It is functionally related to a (S)-1,2-epoxypropane. It is an enantiomer of a (R)-glycidol.

General Description

Glycidol or 2,3-epoxy-1-propanol is a highly reactive epoxy derivative, which is generally used as a monomer in the preparation of many polymers like polyesters,?polycarbonates,?polyurethanes,?and polyamides. It is also used in the preparation of detergents, rubbers, perfumes, fabric dyes, varnishes, cosmetics, and paints.

Purification Methods

[S(-)-isomer, § also available on polymer support, has b 49-50o/7mm, 66-67o/19mm, [ ] D -1 5o(neat)], [R(+)-isomer has b 56 -5 6 . 5o/11mm, d 4 1.117, n D 1.429, [ ] D +15o (neat)]. Purify glycidol by fractional distillation.

Properties of (S)-Oxiranemethanol

Melting point: 72-73 °C
alpha  -15 º (neat)
Boiling point: 66-67 °C19 mm Hg(lit.)
Density  1.116 g/mL at 20 °C(lit.)
refractive index  n20/D 1.433(lit.)
Flash point: 178 °F
storage temp.  -20°C
solubility  Soluble in chloroform, DMSO and methanol.
form  Liquid
pka 14.62±0.10(Predicted)
color  Pale yellow
optical activity [α]20/D 15°, neat
BRN  79783
CAS DataBase Reference 60456-23-7(CAS DataBase Reference)
NIST Chemistry Reference Oxiranemethanol, (S)-(60456-23-7)

Safety information for (S)-Oxiranemethanol

Signal word Danger
Pictogram(s)
ghs
Skull and Crossbones
Acute Toxicity
GHS06
ghs
Health Hazard
GHS08
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H330:Acute toxicity,inhalation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
H341:Germ cell mutagenicity
H350:Carcinogenicity
Precautionary Statement Codes P202:Do not handle until all safety precautions have been read and understood.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for (S)-Oxiranemethanol

InChIKey CTKINSOISVBQLD-VKHMYHEASA-N

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