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HomeProduct name listN,N-Dimethylbenzylamine

N,N-Dimethylbenzylamine

Synonym(s):N-Benzyldimethylamine;BDMA;DMBA;N,N-Dimethylbenzylamine;N-Benzyldimethylamine, BDMA

  • CAS NO.:103-83-3
  • Empirical Formula: C9H13N
  • Molecular Weight: 135.21
  • MDL number: MFCD00026731
  • EINECS: 203-149-1
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-09-12 21:58:09
N,N-Dimethylbenzylamine Structural

What is N,N-Dimethylbenzylamine?

Chemical properties

Colorless to light yellow flammable liquid with ammonia odor. Soluble in ethanol, ether, insoluble in water.

The Uses of N,N-Dimethylbenzylamine

N,N-Dimethylbenzylamine was used in the synthesis of bis[(N,N-dimethylamino)benzyl] selenide. It has been used as catalyst during curing reaction of formulations of diglycidyl ether of bisphenol A and tetrahydrophthalic anhydride. It undergoes directed ortho metalation with butyl lithium. It reacts with methyl iodide to get ammonium salt, which is used as phase transfer catalysts. Further, it is used as a catalyst for the formation of polyurethane foams and epoxy resins.

Preparation

25% Aqueous Dimethylamine, 1088 grams
Benzyl Chloride, 126.6 grams
In the apparatus of Example 1, the benzyl chloride was added dropwise over a two-hour period to the amine (molar ratio 1 to 6) at a rate sufficient to maintain the temperature below 40°C. Stirring was continued at room temperature for an additional hour to insure completion of the reaction denoted by the equation below.
Preparation of N,N-dimethylbenzylamine
Thereafter the reaction mixture was cooled in a separatory funnel while standing in a refrigerator maintained at 5° C. and separated into two layers. The upper oily layer, weighing 111.5g, was removed and steam distilled until no further oleaginous component was observed in the distillate as it came over. The crude distillate was found to contain 103.5g of N,N-dimethylbenzylamine (76.1% of theory), 3.3g of dimethylamine and no quaternary salts. The dimethylamine was distilled off below 29°C under atmospheric pressure from the N,N-dimethylbenzylamine (bp 82°C/18mmHg).

Synthesis Reference(s)

The Journal of Organic Chemistry, 40, p. 531, 1975 DOI: 10.1021/jo00892a043
Synthetic Communications, 6, p. 539, 1976 DOI: 10.1080/00397917608063545

General Description

Benzyldimethylamine appears as a colorless to light yellow liquid with an aromatic odor. Slightly less dense than water and slightly soluble in water. Corrosive to skin, eyes and mucous membranes. Slightly toxic by ingestion, skin absorption and inhalation. Used in the manufacture of adhesives;  dehydrohalogenating catalyst; corrosion inhibitor; acid neutralizer; potting compounds;  cellulose modifier and quaternary ammonium compounds.

Air & Water Reactions

Flammable. Slightly soluble in water.

Reactivity Profile

N,N-Dimethylbenzylamine neutralizes acids on exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides. May attack some plastics [USCG, 1999].

Health Hazard

Inhalation may be fatal as a result of spasm, inflammation and edema of the larynx and bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomitting.

Fire Hazard

Special Hazards of Combustion Products: Toxic vapors are generated when heated.

Safety Profile

Poison by ingestion. Moderately toxic by inhalation and skin contact. Corrosive. A severe eye and skin irritant. Flammable when exposed to heat or flame. When heated to decomposition it emits toxic fumes of NOx

Purification Methods

Dry the amine over KOH pellets and fractionate it over Zn dust in a CO2—free atmosphere. It has a pKa2 5 of 8.25 in 45% aqueous EtOH. Store it under N2 or in a vacuum. The picrate has m 94-95o, and the picrolonate has m 151o (from EtOH). [Skita & Keil Chem Ber 63 34 1930, Coleman J Am Chem Soc 55 3001 1933, Devereux et al. J Chem Soc 2845 1957.] The tetraphenyl borate salt has m 182-185o. [Crane Anal Chem 28 1794 1956, Beilstein 12 IV 2161.]

Properties of N,N-Dimethylbenzylamine

Melting point: -75 °C
Boiling point: 183-184 °C765 mm Hg(lit.)
Density  0.9 g/mL at 25 °C(lit.)
vapor pressure  2.4 hPa (20 °C)
refractive index  n20/D 1.501(lit.)
Flash point: 130 °F
storage temp.  Store below +30°C.
solubility  water: soluble
form  Liquid
pka pK1:9.02(+1) (25°C)
color  Clear colorless to light yellow
PH 10 (10g/l, H2O, 20℃)(saturated solution)
Odor strong fish odor
explosive limit 0.9-6.3%(V)
Water Solubility  8 g/L (20 ºC)
Sensitive  Air Sensitive
BRN  1099620
Stability: Stable. Incompatible with strong acids, strong oxidizing agents.
CAS DataBase Reference 103-83-3(CAS DataBase Reference)
NIST Chemistry Reference Benzenemethanamine, N,N-dimethyl-(103-83-3)
EPA Substance Registry System N,N-Dimethylbenzylamine (103-83-3)

Safety information for N,N-Dimethylbenzylamine

Signal word Danger
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Corrosion
Corrosives
GHS05
ghs
Skull and Crossbones
Acute Toxicity
GHS06
ghs
Environment
GHS09
GHS Hazard Statements H226:Flammable liquids
H301:Acute toxicity,oral
H314:Skin corrosion/irritation
H411:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P273:Avoid release to the environment.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for N,N-Dimethylbenzylamine

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