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HomeProduct name listNickel(II) oxide

Nickel(II) oxide

Synonym(s):Nickel oxide;Nickel Monoxide;Nickelous oxide;Nickel Oxide Sinter 75;Nickel(2+) oxide

  • CAS NO.:1313-99-1
  • Empirical Formula: NiO
  • Molecular Weight: 74.69
  • MDL number: MFCD00011145
  • EINECS: 215-215-7
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-11-19 20:33:22
Nickel(II) oxide Structural

What is Nickel(II) oxide?

Chemical properties

Nickel(II) oxide is Brownish black or black powder.

The Uses of Nickel(II) oxide

Nickel(II) oxide is used in the preparation of nickel alloys including nickel steel alloys, manufacture of glass and porcelain paints. Further nickel oxide is the main component in nickel-iron battery (Edison battery), nickel-cadmium rechargeable battery, and also used in ceramic industry for making frits and porcelain glazes. It also acts as a hydrogenation catalyst. NiO/CNTs (nickel oxide/carbon nanotubes) could be a potential cathode catalyst for oxygen reduction reaction (ORR) in microbial fuel cells (MFCs). It is blended with other high purity oxides and used in a variety of semiconductor applications such as thermistors and varistors.

The Uses of Nickel(II) oxide

Nickel salts, porcelain painting, fuel cell electrodes.

The Uses of Nickel(II) oxide

Nickel oxide nanowires have been studied for use in magnetic memory devices; as well as in luminescent materials.

Preparation

Nickel oxide is prepared by heating pure nickel powder with oxygen at a temperature above 400°C. In some commercial processes, green nickel oxide is made by heating a mixture of nickel powder and water in air at 1,000°C. Adding some nickel oxide to the above mixture enhances the rate of reaction. An alternative method of preparation of the green oxide involves thermal decomposition of an oxo acid salt of nickel at elevated temperatures. Thus, nickel nitrate, nickel sulfate or, more conveniently, nickel carbonate when heated at 1,000°C, yields the green oxide. The black oxide, on the other hand, is produced at a lower temperature from incomplete calcination of the carbonate or nitrate salt at 600°C. The oxygen content of the black form is slight-ly greater than its green counterpart.

Reactions

Nickel(II) oxide is insoluble in water but soluble in acids as long as it has not been ignited at a high temperature (under these latter conditions it is converted into grey-black octahedra having a metallic lustre). It reacts reversibly with hydrogen, the reaction NiO+H2 ? Ni+H20 proceeding from left to right at relatively low temperatures in a stream of hydrogen.

General Description

Nickel(II) oxide (NiO) is a metal oxide based nanomaterial with a good semiconducting property. Nanosized nickel oxide can be found in a variety of morphologies which include nanoflowers, spheres, wires, and tubes. It exhibits high performance in applications which require charge transfer and charge transport based processes. It can be prepared by a variety of physical and thermal methods such as sol-gel, hydrothermal and solvothermal techniques.

Hazard

Confirmed carcinogen.

Flammability and Explosibility

Non flammable

Safety Profile

Confirmed carcinogen with experimental carcinogenic and tumorigenic data. Poison by intratracheal, intravenous, and subcutaneous routes. Mutation data reported. Can react violently with fluorine, hydrogen peroxide, hydrogen sulfide, iodine, barium oxide + air. See also NICKEL COMPOUNDS.

Properties of Nickel(II) oxide

Melting point: 1960 °C
Density  6.67 g/mL at 25 °C(lit.)
solubility  insoluble in H2O; soluble in acid solutions
form  Powder/Solid
color  green
Specific Gravity 6.67
Water Solubility  insoluble
Merck  14,6512
Exposure limits ACGIH: TWA 0.2 mg/m3
NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
Stability: Stable. Incompatible with strong acids.
InChI InChI=1S/Ni.O
CAS DataBase Reference 1313-99-1(CAS DataBase Reference)
EPA Substance Registry System Nickel(II) oxide (1313-99-1)

Safety information for Nickel(II) oxide

Signal word Danger
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
ghs
Health Hazard
GHS08
GHS Hazard Statements H317:Sensitisation, Skin
H372:Specific target organ toxicity, repeated exposure
H413:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P202:Do not handle until all safety precautions have been read and understood.
P260:Do not breathe dust/fume/gas/mist/vapours/spray.
P273:Avoid release to the environment.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P308+P313:IF exposed or concerned: Get medical advice/attention.

Computed Descriptors for Nickel(II) oxide

InChIKey GNRSAWUEBMWBQH-UHFFFAOYSA-N
SMILES O=[Ni]

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