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HomeProduct name listPotassium hydrogen phthalate

Potassium hydrogen phthalate

Synonym(s):Potassium hydrogen phthalate;KHP;Potassium biphthalate;buffer solution;Potassium phthalate monobasic

  • CAS NO.:877-24-7
  • Empirical Formula: C8H5KO4
  • Molecular Weight: 204.22
  • MDL number: MFCD00146206
  • EINECS: 212-889-4
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-12-18 14:07:02
Potassium hydrogen phthalate Structural

What is Potassium hydrogen phthalate?

Chemical properties

white crystalline powder

The Uses of Potassium hydrogen phthalate

As a primary standard for preparing volumetric alkali solutions and as a buffer in pH determinations. Potassium hydrogen phthalate is used as a primary standard for acid- base titrations as well as for calibrating pH meters. It acts as a buffer in pH determination. It finds application as a useful standard for total organic carbon testing.

The Uses of Potassium hydrogen phthalate

As primary standard for preparing volumetric alkali solutions, also as a buffer in pH determinations.

The Uses of Potassium hydrogen phthalate

Potassium hydrogen phthalate [KHP; pH(S) = 4.005 (25 °C)] is a certified secondary standard reference material used as a calibration buffer standard for pH instruments or pH electrodes.

What are the applications of Application

Potassium phthalate monobasic is a primary acid standard for volumetric preparations

General Description

SRM 2185_cert SRM 2185 _SDS

Flammability and Explosibility

Not classified

Purification Methods

Crystallise it first from a dilute aqueous solution of K2CO3, then H2O (3mL/g) between 100o and 0o. Before being used as a standard in volumetric analysis, analytical grade potassium hydrogen phthalate should be dried at 120o for 2hours, then allowed to cool in a desiccator. [Beilstein 9 IV 3169.]

Properties of Potassium hydrogen phthalate

Melting point: 295-300 °C (dec.) (lit.)
Boiling point: 98.5-99.5 ;°C/740 ;mmHg(lit .)
Density  1.006 g/mL at 20 °C
storage temp.  Store at +5°C to +30°C.
solubility  H2O: 100 mg/mL, clear, colorless
form  Solid
color  White
Odor Odorless
PH 4.00-4.02 (25.0℃±0.2℃, 0.05M)
PH Range 3.8 - 4.0 (5% aq. sol.)
Water Solubility  80 G/L (20 ºC)
Merck  14,7612
BRN  3637128
Stability: Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference 877-24-7(CAS DataBase Reference)
EPA Substance Registry System Monopotassium phthalate (877-24-7)

Safety information for Potassium hydrogen phthalate

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
Precautionary Statement Codes P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313:IF SKIN irritation occurs: Get medical advice/attention.
P337+P313:IF eye irritation persists: Get medical advice/attention.

Computed Descriptors for Potassium hydrogen phthalate

InChIKey IWZKICVEHNUQTL-UHFFFAOYSA-M

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