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HomeProduct name listMETHYLENECYCLOHEXANE

METHYLENECYCLOHEXANE

  • CAS NO.:1192-37-6
  • Empirical Formula: C7H12
  • Molecular Weight: 96.17
  • MDL number: MFCD00001661
  • EINECS: 214-752-4
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-12-18 14:08:57
METHYLENECYCLOHEXANE Structural

What is METHYLENECYCLOHEXANE?

Chemical properties

colourless liquid

The Uses of METHYLENECYCLOHEXANE

Methylenecyclohexane is excellent building block for organic molecules.

Synthesis Reference(s)

Journal of the American Chemical Society, 100, p. 3611, 1978 DOI: 10.1021/ja00479a061
The Journal of Organic Chemistry, 48, p. 326, 1983 DOI: 10.1021/jo00151a010
Tetrahedron Letters, 25, p. 4901, 1984 DOI: 10.1016/S0040-4039(01)91254-7

General Description

Methylenecyclohexane ring is obtained by 1,4-addition of 4-pentenylmagnesium bromide to 2-cyano-2-cycloalkenones followed by a Pd(II)-mediated oxidative cyclization. It undergoes gas phase ozonolysis to form secondary organic aerosol (SOA).

Properties of METHYLENECYCLOHEXANE

Melting point: -106.7°C
Boiling point: 102-103 °C (lit.)
Density  0.8 g/mL at 25 °C (lit.)
refractive index  n20/D 1.449(lit.)
Flash point: 20 °F
storage temp.  2-8°C
form  Liquid
color  Clear colorless
BRN  773760
Stability: Stable. Highly flammable. Incompatible with strong oxidizing agents. Refrigerate.
EPA Substance Registry System Cyclohexane, methylene- (1192-37-6)

Safety information for METHYLENECYCLOHEXANE

Signal word Danger
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Health Hazard
GHS08
GHS Hazard Statements H225:Flammable liquids
H304:Aspiration hazard
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233:Keep container tightly closed.
P240:Ground/bond container and receiving equipment.
P241:Use explosion-proof electrical/ventilating/lighting/…/equipment.
P331:Do NOT induce vomiting.
P301+P310:IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

Computed Descriptors for METHYLENECYCLOHEXANE

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