Lithium trifluoromethanesulfonate
Synonym(s):LiTf;Lithium triflate;Trifluoromethanesulfonic acid lithium salt
- CAS NO.:33454-82-9
- Empirical Formula: CF3LiO3S
- Molecular Weight: 156.01
- MDL number: MFCD00013227
- EINECS: 251-528-5
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-10-31 13:32:20
What is Lithium trifluoromethanesulfonate?
Chemical properties
white powder
Properties and Applications
Lithium trifluoromethanesulfonate is highly soluble in water and organic solvents and shows excellent ion conductivity. It is highly soluble in polar organic solvents such as dimethyl carbonate (DMC), diethyl carbonate (DEC), ethyl acetate, and others. This compound exhibits good thermal stability and has a non-coordinating anion (triflate), which helps prevent unwanted reactions with other components in electrochemical systems.
The Uses of Lithium trifluoromethanesulfonate
Lithium trifluoromethanesulfonate is mixed with ceramic filler to prepare polyethylene oxide films in order to improve the electrochemical and mechanical characteristics of the membrane, which is used in the lithium batteries. It acts as a doping salt used in the preparation of nano manganese-composite polymer electrolytes.
General Description
Lithium trifluoromethanesulfonate has been enhanced for energy efficiency.Its electrical conductivity is comparable to lithium perchlorate and lithium hexafluoroarsenate
Synthesis
A 316L stainless steel autoclave was charged with 1678 g of a 10.0% aqueous solution of lithium hydroxide and 424 g of calcium oxide, and the temperature was raised to 85 ℃, and the mixture was stirred for 3 hours. The reaction pressure was controlled by continuously feeding the trifluoromethane sulfonyl fluoride gas. The reaction time is 3.5 hours, then the reaction is kept for 3 hours, and then the temperature is lowered to 25 ℃. The reaction liquid is filtered to obtain the product lithium trifluoromethanesulfonate aqueous solution.
Properties of Lithium trifluoromethanesulfonate
Melting point: | >300 °C (lit.) |
Density | 1,9 g/cm3 |
storage temp. | Inert atmosphere,Room Temperature |
solubility | Water |
form | Powder |
color | White or colorless |
Water Solubility | soluble |
Sensitive | Moisture Sensitive |
BRN | 4301818 |
Stability: | hygroscopic |
CAS DataBase Reference | 33454-82-9(CAS DataBase Reference) |
EPA Substance Registry System | Methanesulfonic acid, trifluoro-, lithium salt (33454-82-9) |
Safety information for Lithium trifluoromethanesulfonate
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for Lithium trifluoromethanesulfonate
Abamectin manufacturer
SRF Limited
New Products
(R)-(-)-2-Amino-1-propanol Tetrahydro-4H-pyran-4-one Bromine 99.5% AR (4 x 500ml) Linseed Oil Extrapure Hydrogen Sulphide Solution Oxalic Acid 0.05 mol/L (0.01N) Solution EDTA 0.1 mol/L (0.2N) for 1000 ml Ferroin 0.025M Solution AR 1,2,3,4-Tetrahydrocarbazol-4-one 4-Hydroxy Carbazole Amino Salicylic Acid. U.S.P. 2 – Methoxy – 5- Sulfamoyl Benzoic acid Acetone Isobutryl oxime ester Sodium Amino Salicylate Dihydrate (PAS Sodium) IP/BP/USP/EP Aloe vera extract 200x Withania somnifera (Ashwagandha Extract) Citrus bioflavonoids Extract Spirulina (Arthrospira platensis) Powder Trikatu Extract Thymol Oil Ethyl 3-(Pyridin-2-Ylamino)Propanoate Bilastine -IP/BP/ Cypermethric Acid Chloride 5-NitrosalicylaldehydeRelated products of tetrahydrofuran
You may like
-
Trifluoromethanesulfonic acid lithium salt 98%View Details
-
Lithium trifluoromethanesulfonate CAS 33454-82-9View Details
33454-82-9 -
Lithium trifluoromethanesulfonate CAS 33454-82-9View Details
33454-82-9 -
Lithium Trifluoromethanesulfonate 98% (HPLC) CAS 33454-82-9View Details
33454-82-9 -
Lithium trifluoromethanesulfonate 97% CAS 33454-82-9View Details
33454-82-9 -
Lithium Trifluoromethanesulfonate CAS 33454-82-9View Details
33454-82-9 -
Lithium trifluoromethanesulfonate CAS 33454-82-9View Details
33454-82-9 -
Lithium trifluoromethanesulphonate, 99.995% trace metals basis CAS 33454-82-9View Details
33454-82-9