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HomeProduct name listLithium trifluoromethanesulfonate

Lithium trifluoromethanesulfonate

Synonym(s):LiTf;Lithium triflate;Trifluoromethanesulfonic acid lithium salt

  • CAS NO.:33454-82-9
  • Empirical Formula: CF3LiO3S
  • Molecular Weight: 156.01
  • MDL number: MFCD00013227
  • EINECS: 251-528-5
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-10-31 13:32:20
Lithium trifluoromethanesulfonate Structural

What is Lithium trifluoromethanesulfonate?

Chemical properties

white powder

Properties and Applications

Lithium trifluoromethanesulfonate is highly soluble in water and organic solvents and shows excellent ion conductivity. It is highly soluble in polar organic solvents such as dimethyl carbonate (DMC), diethyl carbonate (DEC), ethyl acetate, and others. This compound exhibits good thermal stability and has a non-coordinating anion (triflate), which helps prevent unwanted reactions with other components in electrochemical systems.

The Uses of Lithium trifluoromethanesulfonate

Lithium trifluoromethanesulfonate is mixed with ceramic filler to prepare polyethylene oxide films in order to improve the electrochemical and mechanical characteristics of the membrane, which is used in the lithium batteries. It acts as a doping salt used in the preparation of nano manganese-composite polymer electrolytes.

General Description

Lithium trifluoromethanesulfonate has been enhanced for energy efficiency.Its electrical conductivity is comparable to lithium perchlorate and lithium hexafluoroarsenate

Synthesis

A 316L stainless steel autoclave was charged with 1678 g of a 10.0% aqueous solution of lithium hydroxide and 424 g of calcium oxide, and the temperature was raised to 85 ℃, and the mixture was stirred for 3 hours. The reaction pressure was controlled by continuously feeding the trifluoromethane sulfonyl fluoride gas. The reaction time is 3.5 hours, then the reaction is kept for 3 hours, and then the temperature is lowered to 25 ℃. The reaction liquid is filtered to obtain the product lithium trifluoromethanesulfonate aqueous solution. 

Properties of Lithium trifluoromethanesulfonate

Melting point: >300 °C (lit.)
Density  1,9 g/cm3
storage temp.  Inert atmosphere,Room Temperature
solubility  Water
form  Powder
color  White or colorless
Water Solubility  soluble
Sensitive  Moisture Sensitive
BRN  4301818
Stability: hygroscopic
CAS DataBase Reference 33454-82-9(CAS DataBase Reference)
EPA Substance Registry System Methanesulfonic acid, trifluoro-, lithium salt (33454-82-9)

Safety information for Lithium trifluoromethanesulfonate

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P271:Use only outdoors or in a well-ventilated area.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Lithium trifluoromethanesulfonate

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