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HomeProduct name listTrifluoromethanesulfonimide

Trifluoromethanesulfonimide

Synonym(s):Bis(trifluoromethanesulfonyl)amine;Bis(trifluoromethylsulfonyl)amine

  • CAS NO.:82113-65-3
  • Empirical Formula: C2HF6NO4S2
  • Molecular Weight: 281.15
  • MDL number: MFCD00214154
  • EINECS: 435-300-4
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-10-31 13:32:20
Trifluoromethanesulfonimide Structural

What is Trifluoromethanesulfonimide?

Chemical properties

light yellow to brown liquid

The Uses of Trifluoromethanesulfonimide

Trifluoromethanesulfonimide is a strong acid, used in the preparation of highly efficient Lewis acid catalysts.

The Uses of Trifluoromethanesulfonimide

1,1,1-Trifluoro-N-((trifluoromethyl)sulfonyl)methanesulfonamide is commonly used as a strong acid to prepare Lewis Acid catalysts. It can also be used to improve efficiency of graphene/silicon Schottky solar cells by chemical doping and as a solvent for recycling battery electrodes.

The Uses of Trifluoromethanesulfonimide

Trifluoromethanesulfonimide may be used as a catalyst for the preparation of 1-substituted-1H-1,2,3,4-tetrazoles.

What are the applications of Application

Trifluoromethanesulfonimide may be used in the following studies:
As catalyst during the polymerization of octamethylcyclotetrasiloxane in the presence of hexamethyldisiloxane.
As efficient catalyst in the synthesis of various non-reducing disaccharides, via ketopyranosylation of 2,3,4,6-tetra-O-benzyl-1-C-methyl-D-hexopyranoses.
Starting material for preparing the N-fluoro derivative, a reactive fluorinating agent.
As a component of solid polymer electrolytes.

General Description

Bis(trifluoromethane)sulfonimide (TFSI, Tf2N) is utilized as anion species to form 1-ethyl-3-methylimidazolium molten salts. It undergoes acid-base complexation with rod-like poly(2,5-pyridine) to afford highly-ordered lamellar self-assemblies in the hydrated films.

Properties of Trifluoromethanesulfonimide

Melting point: 52-56 °C
Boiling point: 90-91 °C(lit.)
Density  1.36
storage temp.  2-8°C
solubility  800g/l Risk of violent reaction.
form  Crystals
pka -10.42±0.40(Predicted)
color  Colorless to brownish
PH 0.8 (100g/l, H2O, 20℃)Risk of violent reaction.
BRN  4754101
Stability: Stable. Incompatible with strong oxidizing agents. Reacts violently with water.
CAS DataBase Reference 82113-65-3(CAS DataBase Reference)
EPA Substance Registry System Methanesulfonamide, 1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]- (82113-65-3)

Safety information for Trifluoromethanesulfonimide

Signal word Danger
Pictogram(s)
ghs
Corrosion
Corrosives
GHS05
ghs
Skull and Crossbones
Acute Toxicity
GHS06
GHS Hazard Statements H301:Acute toxicity,oral
H318:Serious eye damage/eye irritation
H412:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P273:Avoid release to the environment.
P280:Wear protective gloves/protective clothing/eye protection/face protection.

Computed Descriptors for Trifluoromethanesulfonimide

InChIKey ZXMGHDIOOHOAAE-UHFFFAOYSA-N

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