Trifluoromethanesulfonimide
Synonym(s):Bis(trifluoromethanesulfonyl)amine;Bis(trifluoromethylsulfonyl)amine
- CAS NO.:82113-65-3
- Empirical Formula: C2HF6NO4S2
- Molecular Weight: 281.15
- MDL number: MFCD00214154
- EINECS: 435-300-4
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-12-18 14:15:30
What is Trifluoromethanesulfonimide?
Chemical properties
light yellow to brown liquid
The Uses of Trifluoromethanesulfonimide
Trifluoromethanesulfonimide is a strong acid, used in the preparation of highly efficient Lewis acid catalysts.
The Uses of Trifluoromethanesulfonimide
1,1,1-Trifluoro-N-((trifluoromethyl)sulfonyl)methanesulfonamide is commonly used as a strong acid to prepare Lewis Acid catalysts. It can also be used to improve efficiency of graphene/silicon Schottky solar cells by chemical doping and as a solvent for recycling battery electrodes.
The Uses of Trifluoromethanesulfonimide
Trifluoromethanesulfonimide may be used as a catalyst for the preparation of 1-substituted-1H-1,2,3,4-tetrazoles.
What are the applications of Application
Trifluoromethanesulfonimide may be used in the following studies:
As catalyst during the polymerization of octamethylcyclotetrasiloxane in the presence of hexamethyldisiloxane.
As efficient catalyst in the synthesis of various non-reducing disaccharides, via ketopyranosylation of 2,3,4,6-tetra-O-benzyl-1-C-methyl-D-hexopyranoses.
Starting material for preparing the N-fluoro derivative, a reactive fluorinating agent.
As a component of solid polymer electrolytes.
General Description
Bis(trifluoromethane)sulfonimide (TFSI, Tf2N) is utilized as anion species to form 1-ethyl-3-methylimidazolium molten salts. It undergoes acid-base complexation with rod-like poly(2,5-pyridine) to afford highly-ordered lamellar self-assemblies in the hydrated films.
Properties of Trifluoromethanesulfonimide
Melting point: | 52-56 °C |
Boiling point: | 90-91 °C(lit.) |
Density | 1.36 |
storage temp. | 2-8°C |
solubility | 800g/l Risk of violent reaction. |
form | Crystals |
pka | -10.42±0.40(Predicted) |
color | Colorless to brownish |
PH | 0.8 (100g/l, H2O, 20℃)Risk of violent reaction. |
BRN | 4754101 |
Stability: | Stable. Incompatible with strong oxidizing agents. Reacts violently with water. |
CAS DataBase Reference | 82113-65-3(CAS DataBase Reference) |
EPA Substance Registry System | Methanesulfonamide, 1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]- (82113-65-3) |
Safety information for Trifluoromethanesulfonimide
Signal word | Danger |
Pictogram(s) |
Corrosion Corrosives GHS05 Skull and Crossbones Acute Toxicity GHS06 |
GHS Hazard Statements |
H301:Acute toxicity,oral H318:Serious eye damage/eye irritation H412:Hazardous to the aquatic environment, long-term hazard |
Precautionary Statement Codes |
P273:Avoid release to the environment. P280:Wear protective gloves/protective clothing/eye protection/face protection. |
Computed Descriptors for Trifluoromethanesulfonimide
InChIKey | ZXMGHDIOOHOAAE-UHFFFAOYSA-N |
New Products
(S)-3-Aminobutanenitrile hydrochloride 4-Methylphenylacetic acid N-Boc-D-alaninol N-BOC-D/L-ALANINOL Tert-butyl bis(2-chloroethyl)carbamate N-octanoyl benzotriazole 3-Morpholino-1-(4-nitrophenyl)-5,6-dihydropyridin- 2(1H)-one Furan-2,5-Dicarboxylic Acid S-2-CHLORO PROPIONIC ACID ETHYL ISOCYANOACETATE 2-Bromo-1,3-Bis(Dimethylamino)Trimethinium Hexafluorophosphate 4-IODO BENZOIC ACID 3-NITRO-2-METHYL ANILINE 1-(2,4-DICHLOROPHENYL) ETHANAMINE (2-Hydroxyphenyl)acetonitrile 4-Bromopyrazole 5,6-Dimethoxyindanone 2-(Cyanocyclohexyl)acetic acid 4-methoxy-3,5-dinitropyridine 1-(4-(aminomethyl)benzyl)urea hydrochloride 2-aminopropyl benzoate hydrochloride diethyl 2-(2-((tertbutoxycarbonyl)amino) ethyl)malonate tert-butyl 4- (ureidomethyl)benzylcarbamate Ethyl-2-chloro((4-methoxyphenyl)hydrazono)acetateRelated products of tetrahydrofuran
You may like
-
Bis(trifluoromethanesulfonyl)imide CAS 82113-65-3View Details
82113-65-3 -
Trifluoromethanesulfonimide CASView Details
-
Bis(trifluoromethane)sulfonimide CASView Details
-
1975-50-4 98%View Details
1975-50-4 -
2-HYDROXY BENZYL ALCOHOL 98%View Details
90-01-7 -
2-Chloro-1,3-Bis(Dimethylamino)Trimethinium Hexafluorophosphate 221615-75-4 98%View Details
221615-75-4 -
14714-50-2 (2-Hydroxyphenyl)acetonitrile 98+View Details
14714-50-2 -
118753-70-1 98+View Details
118753-70-1