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HomeProduct name listL(+)-Diethyl L-tartrate

L(+)-Diethyl L-tartrate

Synonym(s):(+)-Diethyl L-tartrate;L-(+)-Tartaric acid diethyl ester

  • CAS NO.:87-91-2
  • Empirical Formula: C8H14O6
  • Molecular Weight: 206.19
  • MDL number: MFCD00009143
  • EINECS: 201-783-3
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-04-23 16:18:34
L(+)-Diethyl L-tartrate Structural

What is L(+)-Diethyl L-tartrate?

Chemical properties

Colorless to light yellow liqui

Chemical properties

Diethyl tartrate has a mild, fruity, wine aroma.

Occurrence

The d-isomer has not been reported found in nature; the l-isomer and the racemic form are of little importance. Reported found in sherry, white and red wine.

The Uses of L(+)-Diethyl L-tartrate

Diethyl L-(+)-Tartrate is used as a chiral reagent in a host of chemical reactions, such as the synthesis of isoquinoline alkaloids and arundic acid, which has been used in acute ischemic stroke thera py.

The Uses of L(+)-Diethyl L-tartrate

(+)-Diethyl L-tartrate is used as a chiral auxiliary in the Sharpless enantioselective epoxidation of allylic alcohols, for Sharpless-type enantioselective oxidation of sulfides to sulfoxides and as a chiral auxiliary in the enantioselective construction of cyclopropanes from allylic alcohols by an asymmetric Simmons-Smith reaction. It is also used as a chiral reagent in a host of chemical reactions, such as the synthesis of isoquinoline alkaloids and arundic acid, which has been used in acute ischemic stroke therapy.

The Uses of L(+)-Diethyl L-tartrate

(+)-Diethyl L-tartrate can be used in the synthesis of biologically active compounds such as (+)-altholactone, (-)-aspicilin, (+)-monomorine I and (+)-(1R,2R,3S,6S)-3,6-di-O-methyl conduritol-E.

General Description

Made from natural tartaric acid

Flammability and Explosibility

Non flammable

Properties of L(+)-Diethyl L-tartrate

Melting point: 17 °C
Boiling point: 280 °C (lit.)
alpha  7.5 º (neat)
Density  1.204 g/mL at 25 °C (lit.)
vapor pressure  0.402Pa at 25℃
FEMA  2378 | DIETHYL TARTRATE
refractive index  n20/D 1.446(lit.)
Flash point: 200 °F
storage temp.  Sealed in dry,Room Temperature
solubility  Chloroform (Slightly), Water (Slightly)
form  Viscous Liquid
pka 11.61±0.20(Predicted)
color  Clear
Odor at 100.00 %. mild fruity wine caramellic
optical activity [α]20/D +8.5°, neat
Water Solubility  insoluble
Merck  14,3855
JECFA Number 622
BRN  1727145
Dielectric constant 4.5(20℃)
CAS DataBase Reference 87-91-2(CAS DataBase Reference)
NIST Chemistry Reference Diethyl tartrate(87-91-2)
EPA Substance Registry System Butanedioic acid, 2,3-dihydroxy- (2R,3R)-, 1,4-diethyl ester (87-91-2)

Safety information for L(+)-Diethyl L-tartrate

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H227:Flammable liquids
Precautionary Statement Codes P403+P235:Store in a well-ventilated place. Keep cool.

Computed Descriptors for L(+)-Diethyl L-tartrate

InChIKey YSAVZVORKRDODB-PHDIDXHHSA-N

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