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HomeProduct name list(+)-Dimethyl L-tartrate

(+)-Dimethyl L-tartrate

Synonym(s):L-(+)-Tartaric acid dimethyl ester

  • CAS NO.:608-68-4
  • Empirical Formula: C6H10O6
  • Molecular Weight: 178.14
  • MDL number: MFCD00064437
  • EINECS: 210-166-8
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-12-18 13:37:16
(+)-Dimethyl L-tartrate Structural

What is (+)-Dimethyl L-tartrate?

Chemical properties

Colorless to light yellow liqui

The Uses of (+)-Dimethyl L-tartrate

(+)-Dimethyl L-tartrate is used as a starting reagent in the synthesis of (+)-Monomorine I, a pyrrolidine-based alkaloid that is a trail pheromone of the Pharaoh’s ant (Monomorium pharaonis).

The Uses of (+)-Dimethyl L-tartrate

(+)-Dimethyl L-tartrate can react with sulfur tetrafluoride to form dimethyl meso-2,3-difluorosuccinate.
It may be used in the synthesis of the following chiral ligands for use in asymmetric synthesis:

  • (2R, 3R)-1,4-dimethoxy-1,1,4,4-tetraphenyl-2,3-butanediol
  • (-)-(4S,5R)-4-(2-pyridyl)-5-(diphenylphosphino)methyl-2,2-dimethyl-1,3-dioxolane (PYDIPHOS)
  • (4R,5R)-α,α,α′,α′-2,2-hexaphenyl-4,5-dimethanol-1,3-dioxolane

Properties of (+)-Dimethyl L-tartrate

Melting point: 57-60 °C (dec.) (lit.)
Boiling point: 163 °C/23 mmHg (lit.)
alpha  21 º (c=10, H2O)
Density  1.238 g/mL at 25 °C (lit.)
refractive index  21 ° (C=2.5, H2O)
Flash point: >230 °F
storage temp.  Inert atmosphere,Room Temperature
pka 11.44±0.20(Predicted)
form  Crystals
color  White
Specific Gravity 1.3046 (50/4℃)
optical activity [α]22/D +21°, c = 2.5 in H2O
Water Solubility  Soluble in water.
BRN  1726256
CAS DataBase Reference 608-68-4(CAS DataBase Reference)
NIST Chemistry Reference Butanedioic acid, 2,3-dihydroxy- [R-(R*,R*)]-, dimethyl ester(608-68-4)
EPA Substance Registry System Butanedioic acid, 2,3-dihydroxy- (2R,3R)-, dimethyl ester (608-68-4)

Safety information for (+)-Dimethyl L-tartrate

Computed Descriptors for (+)-Dimethyl L-tartrate

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