Isobornyl acetate
Synonym(s):Acetic acid isobornyl ester, exo-(1R)-1,7,7-Trimethylbicyclo[2.2.1]hept-2-yl acetate;Isobornyl acetate
- CAS NO.:125-12-2
- Empirical Formula: C12H20O2
- Molecular Weight: 196.29
- MDL number: MFCD00135943
- EINECS: 204-727-6
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-11-20 11:41:24
What is Isobornyl acetate?
Description
Isobornyl acetate has a pleasant, camphor-like odor reminiscent of some varieties of pine needles and hemlock, and a fresh, burning taste. May be prepared by treatment of camphene with acetic acid, usually in the presence of a catalyst; also by acetylation of isobomeol; depending on the starting material (d-camphene or ι-camphene), the resulting acetate may exhibit a slight optical activity; the commercial product is considered to be optically inactive.
Chemical properties
Colorless liquid; pine-needle odor.Soluble in most fixed oils and in mineral oil; insoluble in glycerol and water. Combustible.
Chemical properties
Isobornyl Acetate has
been identified in a number of essential oils. It is a colorless liquid with a pleasant, pine-needle odor. Isobornyl acetate is prepared from camphene and
acetic acid in the presence of acidic catalysts (e.g., sulfuric acid) or on a
styrene–divinylbenzene acid ion-exchanger.
Isobornyl acetate is used in large amounts for perfuming soaps, bath products,
and air fresheners. However, the major use of isobornyl acetate is as an intermediate
in the production of camphor.
Chemical properties
Isobornyl acetate has a pleasant, camphor-like odor reminiscent of some varieties of pine needles and hemlock and a fresh, burning taste
Occurrence
Reported found in thymus, Parmesan cheese, dill herb, Ocimum basilicum, rosemary and custard apple
The Uses of Isobornyl acetate
Isobornyl acetate is one of the most important chemicals used in the perfumery industry. It is used in toiletries and soaps as a flavoring agent and antiseptics. One of main applications is as an intermediate to produce camphor.
The Uses of Isobornyl acetate
Compounding pine-needle odors, toilet waters, bath preparations, antiseptics, theater sprays, soaps, making synthetic camphor, flavoring agent.
Preparation
By treatment of camphene with acetic acid, usually in the presence of a catalyst; also by acetylation of isoborneol; depending on the starting material (d-camphene or l-camphene), the resulting acetate may exhibit slight optical activity; the commercial product is considered to be optically inactive
Aroma threshold values
Aroma characteristics at 1.0%: camphoraceous woody,sweet, citrus and herbal with “Irish Spring” soapy nuances
Taste threshold values
Taste characteristics at 2 to 10 ppm: camphoraceous, woody, terpy and piney with a spicy, herbal and slightly citrus nuance
Properties of Isobornyl acetate
Melting point: | 29°C |
Boiling point: | 229-233 °C (lit.) |
Density | 0.983 g/mL at 25 °C (lit.) |
vapor pressure | 0.13 hPa (20 °C) |
refractive index | n |
FEMA | 2160 | ISOBORNYL ACETATE |
Flash point: | 190 °F |
storage temp. | Store below +30°C. |
solubility | 0.16g/l |
form | Oil |
Specific Gravity | 0.98 |
color | Colourless |
Odor | at 100.00 %. balsam camphor herbal woody sweet |
Water Solubility | Not miscible or difficult to mix with water. |
JECFA Number | 1388 |
BRN | 3197572 |
Stability: | Stable. Flammable. Incompatible with strong oxidizing agents. |
CAS DataBase Reference | 125-12-2(CAS DataBase Reference) |
NIST Chemistry Reference | Isobornyl acetate(125-12-2) |
EPA Substance Registry System | Isobornyl acetate (125-12-2) |
Safety information for Isobornyl acetate
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation |
Precautionary Statement Codes |
P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P332+P313:IF SKIN irritation occurs: Get medical advice/attention. |
Computed Descriptors for Isobornyl acetate
InChIKey | XWIGWPJZNFZLBG-UHFFFAOYSA-N |
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