Fmoc-D-Asparagine
Synonym(s):Fmoc-D -asparagine;Fmoc-D-Asn-OH;N-α-Fmoc-D-asparagine
- CAS NO.:108321-39-7
- Empirical Formula: C19H18N2O5
- Molecular Weight: 354.36
- MDL number: MFCD00062956
- EINECS: 1533716-785-6
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-06-26 13:30:34
What is Fmoc-D-Asparagine?
Chemical properties
white to light yellow crystal powde
The Uses of Fmoc-D-Asparagine
Nα-Fmoc-D-asparagine is an N-Fmoc-protected form of D-Asparagine (A788990). D-Asparagine is an isomer of L-Asparagine (A790005) and is used by bacteria (such as Saccharomyces cerevisiae) as a sole nitrogen source for replication. L-Asparagine is also a competitive inhibitor of staphylococcal L-asparaginase and is used as a reagent to synthesize peptide antibiotics.
Properties of Fmoc-D-Asparagine
Melting point: | ~185 °C (dec.) |
Boiling point: | 678.6±55.0 °C(Predicted) |
alpha | 11.9 º (c=1%, DMF) |
Density | 1.362±0.06 g/cm3(Predicted) |
refractive index | 12 ° (C=1, DMF) |
storage temp. | Sealed in dry,2-8°C |
solubility | Soluble in water or 1% acetic acid |
form | powder to crystal |
pka | 3.68±0.10(Predicted) |
color | White to Almost white |
optical activity | [α]20/D +11.9±1.5°, c = 1% in DMF |
BRN | 8510210 |
CAS DataBase Reference | 108321-39-7(CAS DataBase Reference) |
Safety information for Fmoc-D-Asparagine
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P312:Call a POISON CENTER or doctor/physician if you feel unwell. P302+P352:IF ON SKIN: wash with plenty of soap and water. P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P403+P233:Store in a well-ventilated place. Keep container tightly closed. |
Computed Descriptors for Fmoc-D-Asparagine
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Fmoc
N-(9-Fluorenylmethoxycarbonyloxy)succinimide
ASPARAGINASE
Nalpha-Fmoc-Ndelta-trityl-L-glutamine
FMOC-L-Aspartic acid beta-tert-butyl ester
N-alpha-FMOC-Nepsilon-BOC-L-Lysine
L-Asparagine
Fmoc-D-Asparagine
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