D(+)-10-Camphorsulfonyl chloride
Synonym(s):(+)-Camphor-10-sulfonyl chloride;(1S)-Camphor-10-sulfonic acid chloride
- CAS NO.:21286-54-4
- Empirical Formula: C10H15ClO3S
- Molecular Weight: 250.74
- MDL number: MFCD00064156
- EINECS: 244-314-8
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-08-28 16:27:48
What is D(+)-10-Camphorsulfonyl chloride?
Chemical properties
white to light yellow crystal powde
The Uses of D(+)-10-Camphorsulfonyl chloride
As a useful synthetic intermediate, D(+)-10-Camphorsulfonyl chloride can be used for asymmetric hydroxylation
The Uses of D(+)-10-Camphorsulfonyl chloride
A chiral derivative of Camphor.
What are the applications of Application
(1S)-(+)-10-Camphorsulfonyl Chloride is a chiral derivative of Camphor
Purification Methods
If free from OH bands in the IR, then recrystallise it from Et2O or pet ether; otherwise treat it with SOCl2 at 50o for 30minutes, evaporate, dry the residue over KOH in a vacuum and recrystallise it. The (±)-acid chloride has m 85o [Bartlett & Knox Org Synth 45 14 1965]. Itis characterised as the amide (prisms from EtOH) m 132o, [ ] 17 (+) and (-) 1.5o (EtOH). On repeated recrystallisation from EtOH the anilide has m 120.5-121o, [] 25 +76o (c 1, CHCl3). [Read & Storey J Chem Soc 2761 1930, Sutherland & Shriner J Am Chem Soc 58 62 1936, Halterman et al. J Am Chem Soc 109 8105 1987, Bartlet & Knox Org Synth 45 55 1945, Beilstein 11 IV 650.]
Properties of D(+)-10-Camphorsulfonyl chloride
Melting point: | 67-68 °C |
Boiling point: | 349.4±15.0 °C(Predicted) |
alpha | 33 º (c=1, CHCl3 22 ºC) |
Density | 1.2078 (estimate) |
refractive index | 32 ° (C=1, CHCl3) |
storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
solubility | Chloroform (Slightly), Ethyl Acetate (Slightly) |
form | Crystalline Powder |
color | Off-white to beige |
optical activity | [α]22/D +33°, c = 1 in chloroform |
Sensitive | Moisture Sensitive |
BRN | 3205974 |
CAS DataBase Reference | 21286-54-4(CAS DataBase Reference) |
NIST Chemistry Reference | (+)-Camphor-10-sulfonyl chloride(21286-54-4) |
Safety information for D(+)-10-Camphorsulfonyl chloride
Signal word | Danger |
Pictogram(s) |
Corrosion Corrosives GHS05 |
GHS Hazard Statements |
H314:Skin corrosion/irritation |
Precautionary Statement Codes |
P260:Do not breathe dust/fume/gas/mist/vapours/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P363:Wash contaminated clothing before reuse. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for D(+)-10-Camphorsulfonyl chloride
InChIKey | BGABKEVTHIJBIW-UHFFFAOYSA-N |
Abamectin manufacturer
Radison Labs Private Limited
New Products
4-Aminotetrahydropyran-4-carbonitrile Hydrochloride (R)-3-Aminobutanenitrile Hydrochloride 4-AMINO-TETRAHYDRO-PYRAN-4-CARBOXYLIC ACID HCL 4-(Dimethylamino)tetrahydro-2H-pyran-4-carbonitrile 3-((Dimethylamino)methyl)-5-methylhexan-2-one oxalate 1,4-Dioxa-8-azaspiro[4.5]decane 5-Bromo-2-nitropyridine Nimesulide BP Aceclofenac IP/BP/EP Diclofenac Sodium IP/BP/EP/USP Mefenamic Acid IP/BP/EP/USP Ornidazole IP Diclofenac Potassium SODIUM AAS SOLUTION ZINC AAS SOLUTION BUFFER SOLUTION PH 10.0(BORATE) GOOCH CRUCIBLE SINTERED AQUANIL 5 BERYLLIUM AAS SOLUTION 2-Bromo-1-(bromomethyl)-3-chloro-5-nitrobenzene 2-Bromo-3-nitroaniline N-(3-Hydroxypropyl)-N-methylacetamide 3-Bromo-6-chloropyridazine 4-ethyl-3-nitrobenzoic acidRelated products of tetrahydrofuran
You may like
-
21286-54-4 D-(+)- 10 CAMPHOR SULFONYL CHLORIDE 98%View Details
21286-54-4 -
21286-54-4 99%View Details
21286-54-4 -
(+)-10-Camphorsulfonyl Chloride CAS 21286-54-4View Details
21286-54-4 -
D(+)-10-Camphorsulfonyl chloride 97% CAS 21286-54-4View Details
21286-54-4 -
(1S)-(+)-10-Camphorsulfonyl chloride, 97% CAS 21286-54-4View Details
21286-54-4 -
(1S)-(+)-10-Camphorsulfonyl chloride CAS 21286-54-4View Details
21286-54-4 -
2-(3-(tert-butyl)phenoxy)-2-methylpropanoic acid 1307449-08-6 98%View Details
1307449-08-6 -
Lithium ClavulanateView Details
61177-44-4