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HomeProduct name listCobalt oxide

Cobalt oxide

Synonym(s):Cobaltous oxide

  • CAS NO.:1307-96-6
  • Empirical Formula: CoO
  • Molecular Weight: 74.93
  • MDL number: MFCD00016031
  • EINECS: 215-154-6
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-11-01 18:09:03
Cobalt oxide  Structural

What is Cobalt oxide ?

Description

This is obtained as an olive-green powder by heating the metal in air or steam or by thermal decomposition of the hydroxide, carbonate or nitrate. It has the sodium chloride lattice and is antiferromagnetic below 292°K. When heated in oxygen above 400° the black oxide Co3O4 is obtained. This oxide is isomorphous with magnetite Fe3O4, and has tetrahedrally surrounded cobalt(II) ions and octahedrally surrounded cobalt(III) ions. Both these oxides are readily reduced to the metal by heating in hydrogen or with carbon. The reactions of CoO with silica, alumina and zinc oxide are used to form pigments in the ceramic industry.

Chemical properties

Cobalt oxide is a high-valent oxide of cobalt, with a theoretical cobalt content of 71.06% and an oxygen content of 28.94%, which is a black amorphous powder. Cobalt oxide is a kind of unstable and impossible free state compound, usually refers to the cobalt oxide are attached with a certain amount of cobalt tetraoxide when heated cobalt oxide is reduced to cobalt tetraoxide. The theoretical cobalt content of cobalt tetraoxide is 73.43% and the oxygen content is 26.57%, with the appearance of gray-black or black powder.
Cobalt oxide
The cobalt oxide used in batteries is cobalt tetraoxide, which has a spinel structure. It can be used as anode material for lithium-ion batteries and is also the main raw material for the preparation of lithium cobaltate, the cathode material for lithium-ion batteries.

Physical properties

The commercial product is usually dark grey powder, but the color may vary from olive geeen to brown depending on particle size; density 6.44 g/cm3, which also may vary between 5.7 to 6.7 g/cm3, depending on the method of preparation; melts around 1,830°C; insoluble in water; soluble in acids and alkalis.

The Uses of Cobalt oxide

In pigments for ceramics; glass coloring and decolorization; oxidation catalyst for drying oils, fast-drying paints and varnishes; preparation of cobalt-metal catalysts, Co powder for binder in sintered tungsten carbide; in semiconductors.

The Uses of Cobalt oxide

Cobalt oxide, typically 3.4-4.5%, Molybdenum oxide typically 11.5-14.5% on alumina is used in the preparation of biofuel production by using algae.

Structure and conformation

Green cobalt(II) oxide (CoO) has the rock salt (NaCl) structure. It is easily oxidized with water and oxygen to brown cobalt(III) hydroxide (Co(OH)3). At temperatures of 600℃-700℃, CoO oxidizes to the blue cobalt (II,III) oxide (Co3O4), which has a spinel structure. Black cobalt(III) oxide (Co2O3) also exists. Cobalt oxides are antiferromagnetic at low temperature: CoO (Ne′el temperature 18℃/291K) and Co3O4 (Ne′el temperature: 2233℃/40K), which is analogous to magnetite (Fe3O4), with a mixture of 12 and 13 oxidation states.

Properties of Cobalt oxide

Melting point: 1785 °C
Density  6.45
vapor pressure  0Pa at 20℃
solubility  insoluble in H2O; soluble in acid solutions
form  Powder
color  Green-brown
Specific Gravity 6.45
Water Solubility  insoluble
Sensitive  Air Sensitive
Merck  14,2446
Exposure limits ACGIH: TWA 1 mg/m3
OSHA: TWA 15 mg/m3; TWA 5 mg/m3
Stability: Stability Stable, but may be moisture sensitive.
CAS DataBase Reference 1307-96-6(CAS DataBase Reference)
NIST Chemistry Reference Cobalt monoxide(1307-96-6)
EPA Substance Registry System Cobalt(II) oxide (1307-96-6)

Safety information for Cobalt oxide

Signal word Danger
Pictogram(s)
ghs
Skull and Crossbones
Acute Toxicity
GHS06
ghs
Health Hazard
GHS08
ghs
Environment
GHS09
GHS Hazard Statements H301:Acute toxicity,oral
H317:Sensitisation, Skin
H330:Acute toxicity,inhalation
H334:Sensitisation, respiratory
H410:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P202:Do not handle until all safety precautions have been read and understood.
P260:Do not breathe dust/fume/gas/mist/vapours/spray.
P273:Avoid release to the environment.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.

Computed Descriptors for Cobalt oxide

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