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HomeProduct name listChlorpropham

Chlorpropham

Synonym(s):Chloro-ICP;Chloropropham;Isopropyl N-(3-chlorophenyl)carbamate

  • CAS NO.:101-21-3
  • Empirical Formula: C10H12ClNO2
  • Molecular Weight: 213.66
  • MDL number: MFCD00037108
  • EINECS: 202-925-7
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-12-18 14:08:57
Chlorpropham Structural

What is Chlorpropham?

Chemical properties

beige to brown solid

The Uses of Chlorpropham

Chlorpropham is particularly useful in agricultural settings. It is used in pesticide products for treatment of plants and soil.

The Uses of Chlorpropham

Herbicide; plant growth regulator.

The Uses of Chlorpropham

Preemergent and postemergent herbicide used to regulate plant growth and control of weeds in carrot, onion, garlic and other crops

Definition

ChEBI: A carbamate ester that is the isopropyl ester of 3-chlorophenylcarbamic acid.

General Description

Brown chunky solid.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Chlorpropham is a carbamate ester. Carbamates are chemically similar to, but more reactive than amides. Like amides they form polymers such as polyurethane resins. Carbamates are incompatible with strong acids and bases, and especially incompatible with strong reducing agents such as hydrides. Flammable gaseous hydrogen is produced by the combination of active metals or nitrides with carbamates. Strongly oxidizing acids, peroxides, and hydroperoxides are incompatible with carbamates.

Hazard

Toxic by ingestion.

Fire Hazard

Flash point data for Chlorpropham are not available, however Chlorpropham is probably combustible.

Agricultural Uses

Herbicide, Plant growth regulator: Chlorpropham is a plant growth regulator that is used primarily in the U.S. to inhibit post-harvest potato sprouting. Other uses include pre-emergence control of grass weeds in alfalfa, beans, blueberries, cane berries, carrots, cranberries, ladino clover, garlic, seed grass, onions, spinach, sugar beets, tomatoes, safflower, soybeans, gladioli and woody nursery stock. It is used to control suckers in tobacco

Trade name

ATLAS® CIPC 40; BEET-KLEEN® (with Fenuron® and isopropyl carbanilate); BUDNIP®; CAMPBELL’S® CIPC 40%; CHLORO IPC®; ELBANIL®; FASCO® WY-HOE; FURLOE®; FURLOE® 4EC; JACK WILSON® CHLORO 51 (OIL); LIRO METOXON®; MIRVALE®; MORCRAN® (with n-1-naphthylphthalamic acid); MSS® CICP; NEXOVAL®; PREVENOL® 56; PREVENTOL®; PREVENTOL® 56; PREWEED®; RESIDUREN®; RESIDUREN® EXTRA; SPROUT NIP®; SPROUT-NIP® EC; SPUDNIC®; SPUD-NIE®; STOPGERME®-S; TATERPEX®; TRIPEC® (with carbamic acid, phenyl-, 1-methylethyl ester); TRIHERBICIDE® CIPC; UNICROP® CIPC; WAREFOG®; Y3®

Environmental Fate

Soil. Hydrolyzes in soil forming 3-chloroaniline (Bartha, 1971; Hartley and Kidd, 1987; Smith, 1988; Rajagopal et al., 1989). In soil, Pseudomonas striata Chester, a Flavobacterium sp., an Agrobacterium sp. and an Achromobacter sp. readily degraded chlorpropham to 3-chloroaniline and 2-propanol. Subsequent degradation by enzymatic hydrolysis yielded carbon dioxide, chloride ions and unidentified compounds (Kaufman, 1967; Rajagopal et al., 1989). Hydrolysis products that may form in soil and in microbial cultures include N-phenyl-3-chlorocarbamic acid, 3-chloroaniline, 2-amino-4-chlorophenol, monoisopropyl carbonate, 2-propanol, carbon dioxide and condensation products (Rajagopal et al., 1989). The reported half-lives in soil at 15 and 29°C are 65 and 30 days, respectively (Hartley and Kidd, 1987)
Plant. Chlorpropham is rapidly metabolized in plants (Ashton and Monaco, 1991). Metabolites identified in soybean plants include isopropyl-N-4-hydroxy-3-chlorophenylcarbamate, 1-hydroxy-2-propyl-3′-chlorocarbanilate and isopropyl-N-5-chloro-2-hy
Photolytic. The photodegradation rate of chlorpropham in aqueous solution was enhanced in the presence of a surfactant (TMN-10) (Tanaka et al., 1981). In a later study, Tanaka et al. (1985) studied the photolysis of chlorpropham (50 mg/L) in aque
Chemical/Physical. Emits toxic phosgene fumes when heated to decomposition (Sax and Lewis, 1987). In a 0.50 N sodium hydroxide solution at 20°C, chlorpropham was hydrolyzed to aniline derivatives. The half-life of this reaction was 3.5 days (El-Dib and Aly, 1976). Simple hydrolysis leads to the formation of 3-chlorophenylcarbamic acid and 2-propanol. The acid is very unstable and is spontaneously converted to 3-chloroaniline and carbon dioxide (Still and Herrett, 1976)

Properties of Chlorpropham

Melting point: 41°C
Boiling point: 247°C
Density  1.18
refractive index  nD20 1.5388
Flash point: 247°C
storage temp.  2-8°C
solubility  Chloroform (Slightly), Methanol (Slightly)
form  crystalline
pka 13.06±0.70(Predicted)
color  light tan
Odor faint char. odor
Water Solubility  0.009 g/100 ml very poor
Decomposition  247 ºC
Merck  14,2187
BRN  2211397
Exposure limits An experimental carcinogen and neoplastigen
Stability: Stable. Incompatible with strong acids, strong bases, strong oxidizing agents.
CAS DataBase Reference 101-21-3(CAS DataBase Reference)
IARC 3 (Vol. 12, Sup 7) 1987
NIST Chemistry Reference Chlorpropham(101-21-3)
EPA Substance Registry System Chlorpropham (101-21-3)

Safety information for Chlorpropham

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
ghs
Health Hazard
GHS08
ghs
Environment
GHS09
GHS Hazard Statements H302:Acute toxicity,oral
H351:Carcinogenicity
H373:Specific target organ toxicity, repeated exposure
H411:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P201:Obtain special instructions before use.
P202:Do not handle until all safety precautions have been read and understood.
P260:Do not breathe dust/fume/gas/mist/vapours/spray.
P273:Avoid release to the environment.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P308+P313:IF exposed or concerned: Get medical advice/attention.

Computed Descriptors for Chlorpropham

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