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HomeProduct name listCarbonylbis(triphenylphosphine)rhodium(I) chloride

Carbonylbis(triphenylphosphine)rhodium(I) chloride

Synonym(s):Chlorocarbonylbis(triphenylphosphine)rhodium(I);RhCl(CO)(PPh3)2;Rhodiumbis(triphenylphosphine) carbonyl chloride

  • CAS NO.:13938-94-8
  • Empirical Formula: C37H30ClOP2Rh
  • Molecular Weight: 690.94
  • MDL number: MFCD00044273
  • EINECS: 237-712-8
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-04-23 13:52:06
Carbonylbis(triphenylphosphine)rhodium(I) chloride Structural

What is Carbonylbis(triphenylphosphine)rhodium(I) chloride?

Chemical properties

yellow crystals

The Uses of Carbonylbis(triphenylphosphine)rhodium(I) chloride

Used for cyclometallation.

Properties of Carbonylbis(triphenylphosphine)rhodium(I) chloride

Melting point: 224-227 °C (dec.)(lit.)
storage temp.  Inert atmosphere,Room Temperature
solubility  Soluble in acetone, chloroform, ethanol
form  crystal
color  yellow
BRN  4618896
Exposure limits ACGIH: TWA 0.01 mg/m3; TWA 1 mg/m3
NIOSH: IDLH 2 mg/m3; IDLH 100 mg/m3; TWA 0.001 mg/m3; TWA 0.1 mg/m3
CAS DataBase Reference 13938-94-8(CAS DataBase Reference)

Safety information for Carbonylbis(triphenylphosphine)rhodium(I) chloride

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
Precautionary Statement Codes P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P321:Specific treatment (see … on this label).
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313:IF SKIN irritation occurs: Get medical advice/attention.
P337+P313:IF eye irritation persists: Get medical advice/attention.

Computed Descriptors for Carbonylbis(triphenylphosphine)rhodium(I) chloride

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